The CH+H reaction studied with quantum-mechanical and classical trajectory calculations

Rob Van Harrevelt; Marc C. Van Hemert; George C. Schatz

doi:10.1063/1.1459416

The CH+H reaction studied with quantum-mechanical and classical trajectory calculations

Rob Van Harrevelt, Marc C. Van Hemert^*, George C. Schatz

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The lowest excited ¹Σ _g ⁺-type electronic state of C ₂, the B′ state, had been studied for years. Investigating microwave discharge of various hydrocarbon mixtures by a high-resolution Fourier-transform infrared (FTIR) spectrometers, the B′ ¹Σ _g ⁺→ ¹π _u emission of C ₂ in the infrared was observed. This paper discusses the observation of laser induced fluorescence (LIF) spectra of the D→B′ and C→A transitions of C ₂ in a solid Ne matrix.

Original language	English (US)
Pages (from-to)	6002-6011
Number of pages	10
Journal	Journal of Chemical Physics
Volume	116
Issue number	14
DOIs	https://doi.org/10.1063/1.1459416
State	Published - Apr 8 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1459416

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abstract = "The lowest excited 1Σ g +-type electronic state of C 2, the B′ state, had been studied for years. Investigating microwave discharge of various hydrocarbon mixtures by a high-resolution Fourier-transform infrared (FTIR) spectrometers, the B′ 1Σ g +→ 1π u emission of C 2 in the infrared was observed. This paper discusses the observation of laser induced fluorescence (LIF) spectra of the D→B′ and C→A transitions of C 2 in a solid Ne matrix.",

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AB - The lowest excited 1Σ g +-type electronic state of C 2, the B′ state, had been studied for years. Investigating microwave discharge of various hydrocarbon mixtures by a high-resolution Fourier-transform infrared (FTIR) spectrometers, the B′ 1Σ g +→ 1π u emission of C 2 in the infrared was observed. This paper discusses the observation of laser induced fluorescence (LIF) spectra of the D→B′ and C→A transitions of C 2 in a solid Ne matrix.

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The CH+H reaction studied with quantum-mechanical and classical trajectory calculations

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