The complexing properties of a chiral 18-crown-6 derivative incorporating a 2,5-anhydro-d-mannitol residue. A constitutional and stereochemical means of enhancing complexation

J. Anthony Haslegrave; J. Fraser Stoddart; David J. Thompson

doi:10.1016/S0040-4039(01)93698-6

The complexing properties of a chiral 18-crown-6 derivative incorporating a 2,5-anhydro-d-mannitol residue. A constitutional and stereochemical means of enhancing complexation

J. Anthony Haslegrave^*, J. Fraser Stoddart, David J. Thompson

^*Corresponding author for this work

Chemistry

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Abstract

Measurements of both a thermodynamic and kinetic nature establish that an 18-crown-6 derivative incorporating a 'chiral diethyleneglycol' unit in the shape of a 2,5-anhydro-D-mannitol residue forms extremely strong complexes with alkali metal, NH⁺ ₄, and RNH⁺ ₃ ions.

Original language	English (US)
Pages (from-to)	2279-2282
Number of pages	4
Journal	Tetrahedron Letters
Volume	20
Issue number	24
DOIs	https://doi.org/10.1016/S0040-4039(01)93698-6
State	Published - 1979

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Biochemistry
Drug Discovery
Organic Chemistry

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title = "The complexing properties of a chiral 18-crown-6 derivative incorporating a 2,5-anhydro-d-mannitol residue. A constitutional and stereochemical means of enhancing complexation",

abstract = "Measurements of both a thermodynamic and kinetic nature establish that an 18-crown-6 derivative incorporating a 'chiral diethyleneglycol' unit in the shape of a 2,5-anhydro-D-mannitol residue forms extremely strong complexes with alkali metal, NH+ 4, and RNH+ 3 ions.",

author = "Haslegrave, {J. Anthony} and Stoddart, {J. Fraser} and Thompson, {David J.}",

year = "1979",

doi = "10.1016/S0040-4039(01)93698-6",

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The complexing properties of a chiral 18-crown-6 derivative incorporating a 2,5-anhydro-d-mannitol residue. A constitutional and stereochemical means of enhancing complexation. / Haslegrave, J. Anthony; Stoddart, J. Fraser; Thompson, David J.
In: Tetrahedron Letters, Vol. 20, No. 24, 1979, p. 2279-2282.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The complexing properties of a chiral 18-crown-6 derivative incorporating a 2,5-anhydro-d-mannitol residue. A constitutional and stereochemical means of enhancing complexation

AU - Haslegrave, J. Anthony

AU - Stoddart, J. Fraser

AU - Thompson, David J.

PY - 1979

Y1 - 1979

N2 - Measurements of both a thermodynamic and kinetic nature establish that an 18-crown-6 derivative incorporating a 'chiral diethyleneglycol' unit in the shape of a 2,5-anhydro-D-mannitol residue forms extremely strong complexes with alkali metal, NH+ 4, and RNH+ 3 ions.

AB - Measurements of both a thermodynamic and kinetic nature establish that an 18-crown-6 derivative incorporating a 'chiral diethyleneglycol' unit in the shape of a 2,5-anhydro-D-mannitol residue forms extremely strong complexes with alkali metal, NH+ 4, and RNH+ 3 ions.

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U2 - 10.1016/S0040-4039(01)93698-6

DO - 10.1016/S0040-4039(01)93698-6

M3 - Article

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SN - 0040-4039

VL - 20

SP - 2279

EP - 2282

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 24

ER -

The complexing properties of a chiral 18-crown-6 derivative incorporating a 2,5-anhydro-d-mannitol residue. A constitutional and stereochemical means of enhancing complexation

Abstract

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