The controlled evolution of a polymer single crystal

Xiaogang Liu, Yi Zhang, Dipak K. Goswami, John S. Okasinski, Khalid Salaita, Peng Sun, Michael J. Bedzyk, Chad A. Mirkin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

91 Scopus citations

Abstract

We present a method for controlling the initiation and kinetics of polymer crystal growth using dip-pen nanolithography and an atomic force microscope tip coated with poly-DL-lysine hydrobromide. Triangular prisms of the polymer epitaxially grow on freshly cleaved mica substrates, and their in-plane and out-of-plane growth rates can be controlled by raster scanning the coated tip across the substrate. Atomic force microscope images were concomitantly recorded, providing a set of photographic images of the process as it spans the nanometer-to micrometer-length scales as a function of environmental conditions.

Original languageEnglish (US)
Pages (from-to)1763-1766
Number of pages4
JournalScience
Volume307
Issue number5716
DOIs
StatePublished - Mar 18 2005

ASJC Scopus subject areas

  • General

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