The crystal structure of molecular complex of semicarbazide with nitric acid (1:1)

Z. Wawrzak; P. Grochulski; J. Karniewicz; Z. Gałdecki; M. L. Głowka

doi:10.1080/00150198108238717

The crystal structure of molecular complex of semicarbazide with nitric acid (1:1)

Z. Wawrzak, P. Grochulski, J. Karniewicz, Z. Gałdecki, M. L. Głowka

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The crystal and molecular structure of the equimolar molecular complex of sernicarbazide with nitric acid has been determinated by X-ray diffraction method. The crystals are orthorhombic, space group P2r2t21 with cell parameters (I = 12.83 I), b = 8.62(1), c = 4.76(3)A and four formal molecules per unit cell. The structure was solved by direct methods and refined by full-matrix least-squares to the final R = 0,161 for 414 visually estimated intensities collected on a Weissenberg camera. In the crystals both the semicarbazide and nitric acid molecules exist in ionic form [HzNCO NHNH; NO;] and intermolecular hydrogen bonds are formed.

Original language	English (US)
Pages (from-to)	157-159
Number of pages	3
Journal	Ferroelectrics
Volume	34
Issue number	1
DOIs	https://doi.org/10.1080/00150198108238717
State	Published - Jan 1981

Funding

This research was supported by projects MR.I.5 and MR.I.9 from the Polish Academy of Sciences.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1080/00150198108238717

Cite this

@article{2e5677887511416693eeddc116a3ea8c,

title = "The crystal structure of molecular complex of semicarbazide with nitric acid (1:1)",

abstract = "The crystal and molecular structure of the equimolar molecular complex of sernicarbazide with nitric acid has been determinated by X-ray diffraction method. The crystals are orthorhombic, space group P2r2t21 with cell parameters (I = 12.83 I), b = 8.62(1), c = 4.76(3)A and four formal molecules per unit cell. The structure was solved by direct methods and refined by full-matrix least-squares to the final R = 0,161 for 414 visually estimated intensities collected on a Weissenberg camera. In the crystals both the semicarbazide and nitric acid molecules exist in ionic form [HzNCO NHNH; NO;] and intermolecular hydrogen bonds are formed.",

author = "Z. Wawrzak and P. Grochulski and J. Karniewicz and Z. Ga{\l}decki and G{\l}owka, {M. L.}",

note = "Funding Information: This research was supported by projects MR.I.5 and MR.I.9 from the Polish Academy of Sciences.",

year = "1981",

month = jan,

doi = "10.1080/00150198108238717",

language = "English (US)",

volume = "34",

pages = "157--159",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

number = "1",

}

TY - JOUR

T1 - The crystal structure of molecular complex of semicarbazide with nitric acid (1:1)

AU - Wawrzak, Z.

AU - Grochulski, P.

AU - Karniewicz, J.

AU - Gałdecki, Z.

AU - Głowka, M. L.

N1 - Funding Information: This research was supported by projects MR.I.5 and MR.I.9 from the Polish Academy of Sciences.

PY - 1981/1

Y1 - 1981/1

N2 - The crystal and molecular structure of the equimolar molecular complex of sernicarbazide with nitric acid has been determinated by X-ray diffraction method. The crystals are orthorhombic, space group P2r2t21 with cell parameters (I = 12.83 I), b = 8.62(1), c = 4.76(3)A and four formal molecules per unit cell. The structure was solved by direct methods and refined by full-matrix least-squares to the final R = 0,161 for 414 visually estimated intensities collected on a Weissenberg camera. In the crystals both the semicarbazide and nitric acid molecules exist in ionic form [HzNCO NHNH; NO;] and intermolecular hydrogen bonds are formed.

AB - The crystal and molecular structure of the equimolar molecular complex of sernicarbazide with nitric acid has been determinated by X-ray diffraction method. The crystals are orthorhombic, space group P2r2t21 with cell parameters (I = 12.83 I), b = 8.62(1), c = 4.76(3)A and four formal molecules per unit cell. The structure was solved by direct methods and refined by full-matrix least-squares to the final R = 0,161 for 414 visually estimated intensities collected on a Weissenberg camera. In the crystals both the semicarbazide and nitric acid molecules exist in ionic form [HzNCO NHNH; NO;] and intermolecular hydrogen bonds are formed.

UR - http://www.scopus.com/inward/record.url?scp=0019677475&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0019677475&partnerID=8YFLogxK

U2 - 10.1080/00150198108238717

DO - 10.1080/00150198108238717

M3 - Article

AN - SCOPUS:0019677475

SN - 0015-0193

VL - 34

SP - 157

EP - 159

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1

ER -

The crystal structure of molecular complex of semicarbazide with nitric acid (1:1)

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this