The Crystal Structure of Sodium Perxenate Octahydrate

James A. Ibers; Walter C. Hamilton; D. R. Mackenzie

doi:10.1021/ic50020a015

The Crystal Structure of Sodium Perxenate Octahydrate

James A. Ibers, Walter C. Hamilton, D. R. Mackenzie

Chemistry

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13 Scopus citations

Abstract

Sodium perxenate octahydrate, Na₄XeO₆· 8H₂O, is orthorhombic with cell constants a = 11.86, b = 10.36, c = 10.43 Å., space group Pbcn, Z = 4. A three-dimensional X-ray diffraction investigation has resulted in a complete structure determination. The perxenate ion is approximately a regular octahedron with a mean Xe-O distance of 1.864 ± 0.012 Å. The greatest deviation of an O-Xe-O angle from the ideal 90° is 2.6 ± 0.8°. The two crystallographically independent sodium atoms are surrounded by very distorted octahedra composed of water molecules and perxenate oxygen atoms. A complex array of hydrogen bonds completes the structure.

Original language	English (US)
Pages (from-to)	1412-1416
Number of pages	5
Journal	Inorganic Chemistry
Volume	3
Issue number	10
DOIs	https://doi.org/10.1021/ic50020a015
State	Published - Oct 1 1964

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "The Crystal Structure of Sodium Perxenate Octahydrate",

abstract = "Sodium perxenate octahydrate, Na4XeO6· 8H2O, is orthorhombic with cell constants a = 11.86, b = 10.36, c = 10.43 {\AA}., space group Pbcn, Z = 4. A three-dimensional X-ray diffraction investigation has resulted in a complete structure determination. The perxenate ion is approximately a regular octahedron with a mean Xe-O distance of 1.864 ± 0.012 {\AA}. The greatest deviation of an O-Xe-O angle from the ideal 90° is 2.6 ± 0.8°. The two crystallographically independent sodium atoms are surrounded by very distorted octahedra composed of water molecules and perxenate oxygen atoms. A complex array of hydrogen bonds completes the structure.",

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pages = "1412--1416",

journal = "Inorganic Chemistry",

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TY - JOUR

T1 - The Crystal Structure of Sodium Perxenate Octahydrate

AU - Ibers, James A.

AU - Hamilton, Walter C.

AU - Mackenzie, D. R.

PY - 1964/10/1

Y1 - 1964/10/1

N2 - Sodium perxenate octahydrate, Na4XeO6· 8H2O, is orthorhombic with cell constants a = 11.86, b = 10.36, c = 10.43 Å., space group Pbcn, Z = 4. A three-dimensional X-ray diffraction investigation has resulted in a complete structure determination. The perxenate ion is approximately a regular octahedron with a mean Xe-O distance of 1.864 ± 0.012 Å. The greatest deviation of an O-Xe-O angle from the ideal 90° is 2.6 ± 0.8°. The two crystallographically independent sodium atoms are surrounded by very distorted octahedra composed of water molecules and perxenate oxygen atoms. A complex array of hydrogen bonds completes the structure.

AB - Sodium perxenate octahydrate, Na4XeO6· 8H2O, is orthorhombic with cell constants a = 11.86, b = 10.36, c = 10.43 Å., space group Pbcn, Z = 4. A three-dimensional X-ray diffraction investigation has resulted in a complete structure determination. The perxenate ion is approximately a regular octahedron with a mean Xe-O distance of 1.864 ± 0.012 Å. The greatest deviation of an O-Xe-O angle from the ideal 90° is 2.6 ± 0.8°. The two crystallographically independent sodium atoms are surrounded by very distorted octahedra composed of water molecules and perxenate oxygen atoms. A complex array of hydrogen bonds completes the structure.

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The Crystal Structure of Sodium Perxenate Octahydrate

Abstract

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