The effect of oxide structure and cation reduction potential of vanadates on the selective oxidative dehydrogenation of butane and propane

Ozie S. Owen; Mayfair Kung; Harold H Kung

doi:10.1007/BF00767187

The effect of oxide structure and cation reduction potential of vanadates on the selective oxidative dehydrogenation of butane and propane

Ozie S. Owen, Mayfair Kung, Harold H Kung^*

^*Corresponding author for this work

Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

The oxidative dehydrogenation of butane over a series of orthovanadates of cations of different reduction potentials showed a correlation that the selectivity for dehydrogenation decreased with increasing ease of reduction of the cation. The highest selectivity was observed on Mg orthovanadate. Mg pyrovanadate was nonselective for butane oxidation, but was as selective as Mg orthovanadate in propane oxidation. These results were interpreted by the different structures of the two Mg vanadates.

Original language	English (US)
Pages (from-to)	45-50
Number of pages	6
Journal	Catalysis Letters
Volume	12
Issue number	1-3
DOIs	https://doi.org/10.1007/BF00767187
State	Published - Mar 1 1992

Keywords

Propane
alkane
butane
cation reduction potential
dehydrogenation
oxidation
oxide structure
vanadates

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Catalysis

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10.1007/BF00767187

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title = "The effect of oxide structure and cation reduction potential of vanadates on the selective oxidative dehydrogenation of butane and propane",

abstract = "The oxidative dehydrogenation of butane over a series of orthovanadates of cations of different reduction potentials showed a correlation that the selectivity for dehydrogenation decreased with increasing ease of reduction of the cation. The highest selectivity was observed on Mg orthovanadate. Mg pyrovanadate was nonselective for butane oxidation, but was as selective as Mg orthovanadate in propane oxidation. These results were interpreted by the different structures of the two Mg vanadates.",

keywords = "Propane, alkane, butane, cation reduction potential, dehydrogenation, oxidation, oxide structure, vanadates",

author = "Owen, {Ozie S.} and Mayfair Kung and Kung, {Harold H}",

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doi = "10.1007/BF00767187",

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T1 - The effect of oxide structure and cation reduction potential of vanadates on the selective oxidative dehydrogenation of butane and propane

AU - Owen, Ozie S.

AU - Kung, Mayfair

AU - Kung, Harold H

PY - 1992/3/1

Y1 - 1992/3/1

N2 - The oxidative dehydrogenation of butane over a series of orthovanadates of cations of different reduction potentials showed a correlation that the selectivity for dehydrogenation decreased with increasing ease of reduction of the cation. The highest selectivity was observed on Mg orthovanadate. Mg pyrovanadate was nonselective for butane oxidation, but was as selective as Mg orthovanadate in propane oxidation. These results were interpreted by the different structures of the two Mg vanadates.

AB - The oxidative dehydrogenation of butane over a series of orthovanadates of cations of different reduction potentials showed a correlation that the selectivity for dehydrogenation decreased with increasing ease of reduction of the cation. The highest selectivity was observed on Mg orthovanadate. Mg pyrovanadate was nonselective for butane oxidation, but was as selective as Mg orthovanadate in propane oxidation. These results were interpreted by the different structures of the two Mg vanadates.

KW - Propane

KW - alkane

KW - butane

KW - cation reduction potential

KW - dehydrogenation

KW - oxidation

KW - oxide structure

KW - vanadates

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JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-3

ER -

The effect of oxide structure and cation reduction potential of vanadates on the selective oxidative dehydrogenation of butane and propane

Abstract

Keywords

ASJC Scopus subject areas

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