The effect of pyridine modification of ni-dobdc on co2 capture under humid conditions

Youn Sang Bae*, Jian Liu, Christopher E. Wilmer, Hahnbi Sun, Allison N. Dickey, Min Bum Kim, Annabelle I. Benin, Richard R. Willis, Dushyant Barpaga, M. Douglas LeVan, Randall Q. Snurr

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H2O adsorption while retaining substantial CO2 capacity under the conditions of interest for carbon capture from flue gas.

Original languageEnglish (US)
Pages (from-to)3296-3298
Number of pages3
JournalChemical Communications
Volume50
Issue number25
DOIs
StatePublished - Feb 27 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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