The exclusivity of multivalency in dynamic covalent processes

Jovica D. Badjić; Stuart J. Cantrill; Robert H. Grubbs; Erin N. Guidry; Raul Orenes; J. Fraser Stoddart

doi:10.1002/anie.200453963

The exclusivity of multivalency in dynamic covalent processes

Jovica D. Badjić, Stuart J. Cantrill, Robert H. Grubbs^*, Erin N. Guidry, Raul Orenes, J. Fraser Stoddart

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

Original language	English (US)
Pages (from-to)	3273-3278
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	25
DOIs	https://doi.org/10.1002/anie.200453963
State	Published - Jun 21 2004

Keywords

Metathesis
Molecular recognition
NMR spectroscopy
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200453963

Cite this

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AU - Orenes, Raul

AU - Stoddart, J. Fraser

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N2 - Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

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KW - Metathesis

KW - Molecular recognition

KW - NMR spectroscopy

KW - Supramolecular chemistry

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The exclusivity of multivalency in dynamic covalent processes

Abstract

Keywords

ASJC Scopus subject areas

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