The exclusivity of multivalency in dynamic covalent processes

Jovica D. Badjić; Stuart J. Cantrill; Robert H. Grubbs; Erin N. Guidry; Raul Orenes; J. Fraser Stoddart

doi:10.1002/anie.200453963

The exclusivity of multivalency in dynamic covalent processes

Jovica D. Badjić, Stuart J. Cantrill, Robert H. Grubbs^*, Erin N. Guidry, Raul Orenes, J. Fraser Stoddart

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

Original language	English (US)
Pages (from-to)	3273-3278
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	25
DOIs	https://doi.org/10.1002/anie.200453963
State	Published - Jun 21 2004

Keywords

Metathesis
Molecular recognition
NMR spectroscopy
Supramolecular chemistry

ASJC Scopus subject areas

General Chemistry
Catalysis

Access to Document

10.1002/anie.200453963

Cite this

@article{809267a53e324930acf1635ef5b99365,

title = "The exclusivity of multivalency in dynamic covalent processes",

abstract = "Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.",

keywords = "Metathesis, Molecular recognition, NMR spectroscopy, Supramolecular chemistry",

author = "Badji{\'c}, \{Jovica D.\} and Cantrill, \{Stuart J.\} and Grubbs, \{Robert H.\} and Guidry, \{Erin N.\} and Raul Orenes and Stoddart, \{J. Fraser\}",

year = "2004",

month = jun,

day = "21",

doi = "10.1002/anie.200453963",

language = "English (US)",

volume = "43",

pages = "3273--3278",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "25",

}

TY - JOUR

T1 - The exclusivity of multivalency in dynamic covalent processes

AU - Badjić, Jovica D.

AU - Cantrill, Stuart J.

AU - Grubbs, Robert H.

AU - Guidry, Erin N.

AU - Orenes, Raul

AU - Stoddart, J. Fraser

PY - 2004/6/21

Y1 - 2004/6/21

N2 - Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

AB - Less is more: It is much less efficient to synthesize both components of a multivalent recognition site separately than it is to use one multivalent component to act as a template for the catalytically orchestrated construction of the other component, as demonstrated by the formation of the mechanically interlocked, triply threaded molecular bundle shown. The situation is reiniscent of nature.

KW - Metathesis

KW - Molecular recognition

KW - NMR spectroscopy

KW - Supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=4544225275&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4544225275&partnerID=8YFLogxK

U2 - 10.1002/anie.200453963

DO - 10.1002/anie.200453963

M3 - Article

C2 - 15213952

AN - SCOPUS:4544225275

SN - 1433-7851

VL - 43

SP - 3273

EP - 3278

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 25

ER -

The exclusivity of multivalency in dynamic covalent processes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this