The Infinite Chain Nitride Na5Ba3N. A One-Dimensional Void Metal?

G. Jeffrey Snyder, Arndt Simon*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

The crystal structure of Na5Ba3N was determined from a single crystal grown by a diffusion limited process (Pnma, a = 11.882(2) Å,b = 7.049(1) A, c = 17.792(4) A, Z = 4, R = 0.063). The structure contains Ba3N chains nearly identical with those found in NaBa3N. The structure can be explained in terms of strong Ba—N intrachain ionic bonding and weak Ba—Na metallic bonding separating the chains. Na5Ba3N is a common impurity phase in Na—Ba alloys, which has probably exacerbated the difficulties in determining Na—Ba phase equilibria. Na5Ba3N has the structural characteristics of a one-dimensional void metal.

Original languageEnglish (US)
Pages (from-to)1996-1999
Number of pages4
JournalJournal of the American Chemical Society
Volume117
Issue number7
DOIs
StatePublished - Jan 1 1995

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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