The crystal structure of 2NaPF6·dibenzo-36-crown-12 was determined by X-ray diffraction methods. The 2:1 (metal:ligand) complex crystallises in the monoclinic system, space group P21/n with cell constants of a = 14.189(2), b = 9.372(1), c = 16.750(3) Å, and β = 108.98(1)°. The two NaPF6 units are each coordinated through five oxygen atoms to opposite faces of the macrocycle in a centrosymmetric manner.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry