The isolation and x-ray crystal structure of a complex between sodium hexafluorophosphate and dibenzo-36-crown-12

John M. Maud, J. Fraser Stoddart*, Howard M. Colquhoun, David J. Williams

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The crystal structure of 2NaPF6·dibenzo-36-crown-12 was determined by X-ray diffraction methods. The 2:1 (metal:ligand) complex crystallises in the monoclinic system, space group P21/n with cell constants of a = 14.189(2), b = 9.372(1), c = 16.750(3) Å, and β = 108.98(1)°. The two NaPF6 units are each coordinated through five oxygen atoms to opposite faces of the macrocycle in a centrosymmetric manner.

Original languageEnglish (US)
Pages (from-to)675-679
Number of pages5
JournalPolyhedron
Volume3
Issue number6
DOIs
StatePublished - 1984

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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