The isolation and x-ray crystal structure of an adduct formed between 18-crown-6 and cisplatin

David R. Alston; J. Fraser Stoddart; David J. Williams

doi:10.1039/c39850000532

The isolation and x-ray crystal structure of an adduct formed between 18-crown-6 and cisplatin

David R. Alston^*, J. Fraser Stoddart, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The X-ray structure of the crystalline complex formed between 18-crown-6 and 2 mol. equiv. of cisplatin and dimethylacetamide reveals hydrogen bonding which involves all three hydrogen atoms on both ammine ligands of cisplatin forming bonds to (i) all six oxygen atoms of 18-crown-6, (ii) one chlorine atom on a symmetry-translated cisplatin, and (iii) the carbonyl oxygen atom of dimethylacetamide.

Original language	English (US)
Pages (from-to)	532-533
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/c39850000532
State	Published - 1985

ASJC Scopus subject areas

Molecular Medicine

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abstract = "The X-ray structure of the crystalline complex formed between 18-crown-6 and 2 mol. equiv. of cisplatin and dimethylacetamide reveals hydrogen bonding which involves all three hydrogen atoms on both ammine ligands of cisplatin forming bonds to (i) all six oxygen atoms of 18-crown-6, (ii) one chlorine atom on a symmetry-translated cisplatin, and (iii) the carbonyl oxygen atom of dimethylacetamide.",

author = "Alston, {David R.} and Stoddart, {J. Fraser} and Williams, {David J.}",

year = "1985",

doi = "10.1039/c39850000532",

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N2 - The X-ray structure of the crystalline complex formed between 18-crown-6 and 2 mol. equiv. of cisplatin and dimethylacetamide reveals hydrogen bonding which involves all three hydrogen atoms on both ammine ligands of cisplatin forming bonds to (i) all six oxygen atoms of 18-crown-6, (ii) one chlorine atom on a symmetry-translated cisplatin, and (iii) the carbonyl oxygen atom of dimethylacetamide.

AB - The X-ray structure of the crystalline complex formed between 18-crown-6 and 2 mol. equiv. of cisplatin and dimethylacetamide reveals hydrogen bonding which involves all three hydrogen atoms on both ammine ligands of cisplatin forming bonds to (i) all six oxygen atoms of 18-crown-6, (ii) one chlorine atom on a symmetry-translated cisplatin, and (iii) the carbonyl oxygen atom of dimethylacetamide.

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The isolation and x-ray crystal structure of an adduct formed between 18-crown-6 and cisplatin

Abstract

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