The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH3F

V. A. Apkarian; Eric Weitz

doi:10.1016/0009-2614(80)80606-3

The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH₃F

V. A. Apkarian^*, Eric Weitz

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Subsequent to exciting v₃ by a CO₂ laser pulse, fluorescence has been detected from 2v₃ of CH₃F trapped in rare gas matrices. 2v₃ is activated by V-V energy transfer and deactivates at twice the rate of v₃ relaxation. A kinetic model is presented to interpret these observations.

Original language	English (US)
Pages (from-to)	68-74
Number of pages	7
Journal	Chemical Physics Letters
Volume	76
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(80)80606-3
State	Published - Jan 1 1980

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(80)80606-3

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title = "The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH3F",

abstract = "Subsequent to exciting v3 by a CO2 laser pulse, fluorescence has been detected from 2v3 of CH3F trapped in rare gas matrices. 2v3 is activated by V-V energy transfer and deactivates at twice the rate of v3 relaxation. A kinetic model is presented to interpret these observations.",

author = "Apkarian, {V. A.} and Eric Weitz",

year = "1980",

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AU - Apkarian, V. A.

AU - Weitz, Eric

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N2 - Subsequent to exciting v3 by a CO2 laser pulse, fluorescence has been detected from 2v3 of CH3F trapped in rare gas matrices. 2v3 is activated by V-V energy transfer and deactivates at twice the rate of v3 relaxation. A kinetic model is presented to interpret these observations.

AB - Subsequent to exciting v3 by a CO2 laser pulse, fluorescence has been detected from 2v3 of CH3F trapped in rare gas matrices. 2v3 is activated by V-V energy transfer and deactivates at twice the rate of v3 relaxation. A kinetic model is presented to interpret these observations.

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DO - 10.1016/0009-2614(80)80606-3

M3 - Article

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SP - 68

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JF - Chemical Physics Letters

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ER -

The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH₃F

Abstract

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