The kinetics of vibrational energy transfer and relaxation processes in matrix isolated CH3F

V. A. Apkarian*, Eric Weitz

*Corresponding author for this work

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

Subsequent to exciting v3 by a CO2 laser pulse, fluorescence has been detected from 2v3 of CH3F trapped in rare gas matrices. 2v3 is activated by V-V energy transfer and deactivates at twice the rate of v3 relaxation. A kinetic model is presented to interpret these observations.

Original languageEnglish (US)
Pages (from-to)68-74
Number of pages7
JournalChemical Physics Letters
Volume76
Issue number1
DOIs
StatePublished - Jan 1 1980

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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