Subsequent to exciting v3 by a CO2 laser pulse, fluorescence has been detected from 2v3 of CH3F trapped in rare gas matrices. 2v3 is activated by V-V energy transfer and deactivates at twice the rate of v3 relaxation. A kinetic model is presented to interpret these observations.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry