The Lanthanide Contraction beyond Coordination Chemistry

Geoffroy Ferru, Benjamin Reinhart, Mrinal K. Bera, Monica Olvera De La Cruz, Baofu Qiao*, Ross J. Ellis

*Corresponding author for this work

Research output: Contribution to journalArticle

18 Scopus citations

Abstract

The lanthanide contraction is conceptualized traditionally through coordination chemistry. Here we break this mold in a structural study of lanthanide ions dissolved in an amphiphilic liquid. The lanthanide contraction perturbs the weak interactions between molecular aggregates that drive mesoscale assembly and emergent behavior. The weak interactions correlate with lanthanide ion transport properties, suggesting new strategies for rare-earth separation that exploit forces outside of the coordination sphere. Outside chances: The lanthanide contraction manifests outside of the coordination sphere, influencing mesoscale ordering and emergent material properties that impact important applications.

Original languageEnglish (US)
Pages (from-to)6899-6904
Number of pages6
JournalChemistry - A European Journal
Volume22
Issue number20
DOIs
StatePublished - May 10 2016

Keywords

  • atomistic simulation
  • coordination
  • lanthanide contraction
  • mesoscale interactions
  • small-angle X-ray scattering

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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