The mixed polychalcogenorhenate(IV) anions [Re4Q4(S3)4(S4) 2]4- (Q=Se, Te): Syntheses and crystal structures of [NMe4]5 [Me2NH2]3[Re4Se4(S 3)4(S4)2]2 ·2.25H2O

Y. V. Mironov; M. A. Pell; T. E. Albrecht-Schmitt; J. A. Ibers

doi:10.1021/ic010434a

The mixed polychalcogenorhenate(IV) anions [Re₄Q₄(S₃)₄(S₄) ₂]^4- (Q=Se, Te): Syntheses and crystal structures of [NMe₄]₅ [Me₂NH₂]₃[Re₄Se₄(S ₃)₄(S₄)₂]₂ ·2.25H₂O

Y. V. Mironov, M. A. Pell, T. E. Albrecht-Schmitt, J. A. Ibers^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The Re(IV) mixed polychalcogenides [NMe₄]₅[Me₂NH₂]₃[Re ₄Se₄(S₃)₄(S₄) ₂]₂·2.25H₂O (1) and [NH₄]₄[Re₄Te₄(S₃) ₄(S₄)₂]·8H₂O (2) have been synthesized by the reaction of Re₄Se₄(TeCl₂)₄Cl₈ with ammonium polysulfide, NMe₄Cl, and Me₂NH₂Cl in water (1) or Re₄Te₄(TeCl₂)₄Cl₈ with ammonium polysulfide in water (2). Both compounds contain Re₄Q₄ cubane-like clusters (Q=Se (1), Te (2)). Each cluster is additionally chelated by two trans S₄^2- ligands and four S₃^2- ligands.

Original language	English (US)
Pages (from-to)	5472-5474
Number of pages	3
Journal	Inorganic chemistry
Volume	40
Issue number	21
DOIs	https://doi.org/10.1021/ic010434a
State	Published - Oct 8 2001
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic010434a

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@article{27773ab30f3443aa8a5993e668e290a6,

title = "The mixed polychalcogenorhenate(IV) anions [Re4Q4(S3)4(S4) 2]4- (Q=Se, Te): Syntheses and crystal structures of [NMe4]5 [Me2NH2]3[Re4Se4(S 3)4(S4)2]2 ·2.25H2O",

abstract = "The Re(IV) mixed polychalcogenides [NMe4]5[Me2NH2]3[Re 4Se4(S3)4(S4) 2]2·2.25H2O (1) and [NH4]4[Re4Te4(S3) 4(S4)2]·8H2O (2) have been synthesized by the reaction of Re4Se4(TeCl2)4Cl8 with ammonium polysulfide, NMe4Cl, and Me2NH2Cl in water (1) or Re4Te4(TeCl2)4Cl8 with ammonium polysulfide in water (2). Both compounds contain Re4Q4 cubane-like clusters (Q=Se (1), Te (2)). Each cluster is additionally chelated by two trans S42- ligands and four S32- ligands.",

author = "Mironov, {Y. V.} and Pell, {M. A.} and Albrecht-Schmitt, {T. E.} and Ibers, {J. A.}",

year = "2001",

month = oct,

day = "8",

doi = "10.1021/ic010434a",

language = "English (US)",

volume = "40",

pages = "5472--5474",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

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TY - JOUR

T1 - The mixed polychalcogenorhenate(IV) anions [Re4Q4(S3)4(S4) 2]4- (Q=Se, Te)

T2 - Syntheses and crystal structures of [NMe4]5 [Me2NH2]3[Re4Se4(S 3)4(S4)2]2 ·2.25H2O

AU - Mironov, Y. V.

AU - Pell, M. A.

AU - Albrecht-Schmitt, T. E.

AU - Ibers, J. A.

PY - 2001/10/8

Y1 - 2001/10/8

N2 - The Re(IV) mixed polychalcogenides [NMe4]5[Me2NH2]3[Re 4Se4(S3)4(S4) 2]2·2.25H2O (1) and [NH4]4[Re4Te4(S3) 4(S4)2]·8H2O (2) have been synthesized by the reaction of Re4Se4(TeCl2)4Cl8 with ammonium polysulfide, NMe4Cl, and Me2NH2Cl in water (1) or Re4Te4(TeCl2)4Cl8 with ammonium polysulfide in water (2). Both compounds contain Re4Q4 cubane-like clusters (Q=Se (1), Te (2)). Each cluster is additionally chelated by two trans S42- ligands and four S32- ligands.

AB - The Re(IV) mixed polychalcogenides [NMe4]5[Me2NH2]3[Re 4Se4(S3)4(S4) 2]2·2.25H2O (1) and [NH4]4[Re4Te4(S3) 4(S4)2]·8H2O (2) have been synthesized by the reaction of Re4Se4(TeCl2)4Cl8 with ammonium polysulfide, NMe4Cl, and Me2NH2Cl in water (1) or Re4Te4(TeCl2)4Cl8 with ammonium polysulfide in water (2). Both compounds contain Re4Q4 cubane-like clusters (Q=Se (1), Te (2)). Each cluster is additionally chelated by two trans S42- ligands and four S32- ligands.

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U2 - 10.1021/ic010434a

DO - 10.1021/ic010434a

M3 - Article

C2 - 11578197

AN - SCOPUS:0035828733

SN - 0020-1669

VL - 40

SP - 5472

EP - 5474

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 21

ER -

The mixed polychalcogenorhenate(IV) anions [Re₄Q₄(S₃)₄(S₄) ₂]^4- (Q=Se, Te): Syntheses and crystal structures of [NMe₄]₅ [Me₂NH₂]₃[Re₄Se₄(S ₃)₄(S₄)₂]₂ ·2.25H₂O

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CCDC 173624: Experimental Crystal Structure Determination

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The mixed polychalcogenorhenate(IV) anions [Re4Q4(S3)4(S4) 2]4- (Q=Se, Te): Syntheses and crystal structures of [NMe4]5 [Me2NH2]3[Re4Se4(S 3)4(S4)2]2 ·2.25H2O

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CCDC 173624: Experimental Crystal Structure Determination

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The mixed polychalcogenorhenate(IV) anions [Re₄Q₄(S₃)₄(S₄) ₂]^4- (Q=Se, Te): Syntheses and crystal structures of [NMe₄]₅ [Me₂NH₂]₃[Re₄Se₄(S ₃)₄(S₄)₂]₂ ·2.25H₂O