The Next-Generation of Nonlinear Optical Materials: Rb3Ba3Li2Al4B6O20F—Synthesis, Characterization, and Crystal Growth

Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli*, Shiv Halasyamani

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Nonlinear optical (NLO) materials are of intense academic and technological interest attributable to their ability to generate coherent radiation over a range of different wavelengths. The requirements for a viable NLO material are rather strict, and their discovery has mainly been serendipitous. This study reports synthesis, characterization, and, most importantly, growth of large single crystals of a technologically viable NLO material—Rb3Ba3Li2Al4B6O20F. Through the judicious selection of cations, Rb3Ba3Li2Al4B6O20F exhibits a 3D structure that facilitates the growth of large single crystals along the optical axis direction. Measurements on these crystals indicate that Rb3Ba3Li2Al4B6O20F exhibits a moderate birefringence of 0.057 at 1064 nm enabling Type I phase-matching down to 243 nm. Theoretical calculations indicate the symmetry adapted mode displacement (SAMD) parameter scales with the second-harmonic generation intensity.

Original languageEnglish (US)
Article number1700840
JournalAdvanced Optical Materials
Volume5
Issue number23
DOIs
StatePublished - Dec 1 2017

Keywords

  • RbBaLiAlBOF
  • borates
  • deep-UV
  • nonlinear optical materials
  • second-harmonic generation

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics

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