The oxidation of tungsten carbonyl in carbon tetrachloride

Richard B. Silverman; R. A. Olofson

doi:10.1039/C19680001313

The oxidation of tungsten carbonyl in carbon tetrachloride

Richard B. Silverman^*, R. A. Olofson

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Original language	English (US)
Pages (from-to)	1313
Number of pages	1
Journal	Analytical Proceedings
Issue number	21
DOIs	https://doi.org/10.1039/C19680001313
State	Published - 1968

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/C19680001313

Cite this

@article{47cbb24069874d12ba1800450cee8704,

title = "The oxidation of tungsten carbonyl in carbon tetrachloride",

author = "Silverman, {Richard B.} and Olofson, {R. A.}",

note = "Funding Information: Secondly, a series of reactions requiring initial attack of radical reagents on carbon of W(CO), and derivatives is predicted, and the invention of new selective oxidation methods, including our own derived scheme for allylic hydroxylation, is anticipated. Finally, with the aim of determining the import- ance of trace oxygen as a synergist or inhibitor, a re-investigation of the numerous polymerization systems which use metal carbonyl-halogenocarbon initiators now becomes desirable. We thank the -Alfred P. Sloan Foundation and Eli Lilly and Co. for financial support. (Received, May 20th, 1968; Corn. 636.) t This compound is synthesized (60%) by the alkylation of tetramethylammonium benzoylpentacarbonyltung- state(0) (ref. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.",

year = "1968",

doi = "10.1039/C19680001313",

language = "English (US)",

pages = "1313",

journal = "Analytical Proceedings",

issn = "0009-241X",

number = "21",

}

TY - JOUR

T1 - The oxidation of tungsten carbonyl in carbon tetrachloride

AU - Silverman, Richard B.

AU - Olofson, R. A.

N1 - Funding Information: Secondly, a series of reactions requiring initial attack of radical reagents on carbon of W(CO), and derivatives is predicted, and the invention of new selective oxidation methods, including our own derived scheme for allylic hydroxylation, is anticipated. Finally, with the aim of determining the import- ance of trace oxygen as a synergist or inhibitor, a re-investigation of the numerous polymerization systems which use metal carbonyl-halogenocarbon initiators now becomes desirable. We thank the -Alfred P. Sloan Foundation and Eli Lilly and Co. for financial support. (Received, May 20th, 1968; Corn. 636.) t This compound is synthesized (60%) by the alkylation of tetramethylammonium benzoylpentacarbonyltung- state(0) (ref. Copyright: Copyright 2007 Elsevier B.V., All rights reserved.

PY - 1968

Y1 - 1968

UR - http://www.scopus.com/inward/record.url?scp=37049132662&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049132662&partnerID=8YFLogxK

U2 - 10.1039/C19680001313

DO - 10.1039/C19680001313

M3 - Article

AN - SCOPUS:37049132662

SP - 1313

JO - Analytical Proceedings

JF - Analytical Proceedings

SN - 0009-241X

IS - 21

ER -

The oxidation of tungsten carbonyl in carbon tetrachloride

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this