The panoscopic approach to high performance thermoelectrics

Li Dong Zhao, Vinayak P. Dravid, Mercouri G. Kanatzidis*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

859 Scopus citations


This review discusses recent developments and current research in high performance bulk thermoelectric materials, comprising nanostructuring, mesostructuring, band alignment, band engineering and synergistically defining key strategies for boosting the thermoelectric performance. To date, the dramatic enhancements in the figure of merit achieved in bulk thermoelectric materials have come either from the reduction in lattice thermal conductivity or improvement in power factors, or both of them. Here, we summarize these relationships between very large reduction of the lattice thermal conductivity with all-scale hierarchical architecturing, large enhanced Seebeck coefficients with intra-matrix electronic structure engineering, and control of the carrier mobility with matrix/inclusion band alignment, which enhance the power factor and reduce the lattice thermal conductivity. The new concept of hierarchical compositionally alloyed nanostructures to achieve these effects is presented. Systems based on PbTe, PbSe and PbS in which spectacular advances have been demonstrated are given particular emphasis. A discussion of future possible strategies is aimed at enhancing the thermoelectric figure of merit of these materials.

Original languageEnglish (US)
Pages (from-to)251-268
Number of pages18
JournalEnergy and Environmental Science
Issue number1
StatePublished - Jan 2014

ASJC Scopus subject areas

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution


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