The role of strontium in modifying aluminium-silicon alloys

M. Timpel, N. Wanderka*, R. Schlesiger, T. Yamamoto, N. Lazarev, D. Isheim, G. Schmitz, S. Matsumura, J. Banhart

*Corresponding author for this work

Research output: Contribution to journalArticle

196 Scopus citations

Abstract

Small amounts of strontium can transform the morphology of the eutectic silicon phase present in Al-Si casting alloys from coarse plate-like to fine fibrous networks. In order to understand this industrially important but hitherto insufficiently understood effect, the strontium distribution was studied in atomic resolution by atom probe tomography and in nanometre resolution by transmission electron microscopy. The combined investigations indicate that Sr co-segregates with Al and Si within the eutectic Si phase. Two types of segregations were found: (i) nanometre-thin rod-like co-segregations of type I are responsible for the formation of multiple twins in a Si crystal and enable its growth in different crystallographic directions; (ii) type II segregations come as more extended structures, restrict growth of a Si crystal and control its branching. We show how Sr enables both kinds of mechanisms previously postulated in the literature, namely "impurity-induced twinning" (via type I) and growth restriction of eutectic Si phase (via type II).

Original languageEnglish (US)
Pages (from-to)3920-3928
Number of pages9
JournalActa Materialia
Volume60
Issue number9
DOIs
StatePublished - May 2012

Keywords

  • Al-Si-based alloys
  • Atom probe tomography
  • Eutectic modification
  • Transmission electron microscopy

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

Fingerprint Dive into the research topics of 'The role of strontium in modifying aluminium-silicon alloys'. Together they form a unique fingerprint.

  • Cite this

    Timpel, M., Wanderka, N., Schlesiger, R., Yamamoto, T., Lazarev, N., Isheim, D., Schmitz, G., Matsumura, S., & Banhart, J. (2012). The role of strontium in modifying aluminium-silicon alloys. Acta Materialia, 60(9), 3920-3928. https://doi.org/10.1016/j.actamat.2012.03.031