Abstract
A chiral 30-crown-10 derivative, DD-(2), has been prepared from 1,4:3,6-dianhydro-D-mannitol, D-(1), and shown by X-ray crystallography and dynamic 13C n.m.r. spectroscopy to adopt, in both the solid state and in solution, a 'face-to-back' conformation which must undergo substantial change in order to create the hydrophilic cavity necessary for the formation of complexes with Li+, Na+, K+, Rb+, NH4+, MeNH3+, and Bu tNH3+ ions.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 430-432 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 9 |
| DOIs | |
| State | Published - Jan 1 1981 |
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ASJC Scopus subject areas
- Molecular Medicine
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The solid state and solution conformational behaviour of a chiral 30-crown-10 derivative synthesised from 1,4:3,6-dianhydro-D-mannitol; X-ray crystal structure. / Metcalfe, Janet C.; Stoddart, J. Fraser; Jones, Geraint; Crawshaw, Thomas H.; Quick, Andrew; Williams, David J.
In: Journal of the Chemical Society, Chemical Communications, No. 9, 01.01.1981, p. 430-432.Research output: Contribution to journal › Article
TY - JOUR
T1 - The solid state and solution conformational behaviour of a chiral 30-crown-10 derivative synthesised from 1,4:3,6-dianhydro-D-mannitol; X-ray crystal structure
AU - Metcalfe, Janet C.
AU - Stoddart, J. Fraser
AU - Jones, Geraint
AU - Crawshaw, Thomas H.
AU - Quick, Andrew
AU - Williams, David J.
PY - 1981/1/1
Y1 - 1981/1/1
N2 - A chiral 30-crown-10 derivative, DD-(2), has been prepared from 1,4:3,6-dianhydro-D-mannitol, D-(1), and shown by X-ray crystallography and dynamic 13C n.m.r. spectroscopy to adopt, in both the solid state and in solution, a 'face-to-back' conformation which must undergo substantial change in order to create the hydrophilic cavity necessary for the formation of complexes with Li+, Na+, K+, Rb+, NH4+, MeNH3+, and Bu tNH3+ ions.
AB - A chiral 30-crown-10 derivative, DD-(2), has been prepared from 1,4:3,6-dianhydro-D-mannitol, D-(1), and shown by X-ray crystallography and dynamic 13C n.m.r. spectroscopy to adopt, in both the solid state and in solution, a 'face-to-back' conformation which must undergo substantial change in order to create the hydrophilic cavity necessary for the formation of complexes with Li+, Na+, K+, Rb+, NH4+, MeNH3+, and Bu tNH3+ ions.
UR - http://www.scopus.com/inward/record.url?scp=37049099483&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049099483&partnerID=8YFLogxK
U2 - 10.1039/c39810000430
DO - 10.1039/c39810000430
M3 - Article
AN - SCOPUS:37049099483
SP - 430
EP - 432
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 9
ER -