The solid-state self-organisation of a self-assembled [2]catenane

David B. Amabilino; Peter R. Ashton; J. Fraser Stoddart; Stephan Menzer; David J. Williams

doi:10.1039/C39940002475

The solid-state self-organisation of a self-assembled [2]catenane

David B. Amabilino^*, Peter R. Ashton, J. Fraser Stoddart, Stephan Menzer, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The reluctance of a [2]catanane, comprised cf macrocycles incorporating π-donors and π-acceptors, to be catenated further to form a [3]catenane may be explained by the molecular arrangement revealed in the solid-state structure of the [2]catenane, which shows all aromatic units to be involved in intramolecular π-π stacking interactions; moreover, the molecules self-organise in the solid-state to form a quilt-like two-dimensional array by virtue of intermolecular π-π stacking interactions.

Original language	English (US)
Pages (from-to)	2475-2478
Number of pages	4
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39940002475
State	Published - Dec 1 1994

ASJC Scopus subject areas

Molecular Medicine

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title = "The solid-state self-organisation of a self-assembled [2]catenane",

abstract = "The reluctance of a [2]catanane, comprised cf macrocycles incorporating π-donors and π-acceptors, to be catenated further to form a [3]catenane may be explained by the molecular arrangement revealed in the solid-state structure of the [2]catenane, which shows all aromatic units to be involved in intramolecular π-π stacking interactions; moreover, the molecules self-organise in the solid-state to form a quilt-like two-dimensional array by virtue of intermolecular π-π stacking interactions.",

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AU - Menzer, Stephan

AU - Williams, David J.

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N2 - The reluctance of a [2]catanane, comprised cf macrocycles incorporating π-donors and π-acceptors, to be catenated further to form a [3]catenane may be explained by the molecular arrangement revealed in the solid-state structure of the [2]catenane, which shows all aromatic units to be involved in intramolecular π-π stacking interactions; moreover, the molecules self-organise in the solid-state to form a quilt-like two-dimensional array by virtue of intermolecular π-π stacking interactions.

AB - The reluctance of a [2]catanane, comprised cf macrocycles incorporating π-donors and π-acceptors, to be catenated further to form a [3]catenane may be explained by the molecular arrangement revealed in the solid-state structure of the [2]catenane, which shows all aromatic units to be involved in intramolecular π-π stacking interactions; moreover, the molecules self-organise in the solid-state to form a quilt-like two-dimensional array by virtue of intermolecular π-π stacking interactions.

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The solid-state self-organisation of a self-assembled [2]catenane

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