The solid state structures of a [3]rotaxane and its [3]pseudorotaxane precursor

Peter R. Ashton; Peter T. Glink; J. Fraser Stoddart; Stephan Menzer; Peter A. Tasker; Andrew J P White; David J. Williams

doi:10.1016/0040-4039(96)01327-5

The solid state structures of a [3]rotaxane and its [3]pseudorotaxane precursor

Peter R. Ashton, Peter T. Glink, J. Fraser Stoddart^*, Stephan Menzer, Peter A. Tasker, Andrew J P White, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The solid state structures of a [3]pseudorotaxane - formed from a bis(azidomethyl)-substituted p-xylene-α,α'-dibenzylammonium dication and two dibenzo-24-crown-8 rings - and a [3]rotaxane derived from it - by two dipolar cycloadditions of the azidomethyl groups with di-t-butyl acetylenedicarboxylate - are described. The (super)structures are remarkably similar in their geometries and packing.

Original language	English (US)
Pages (from-to)	6217-6220
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	34
DOIs	https://doi.org/10.1016/0040-4039(96)01327-5
State	Published - Aug 19 1996

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "The solid state structures of a [3]rotaxane and its [3]pseudorotaxane precursor",

abstract = "The solid state structures of a [3]pseudorotaxane - formed from a bis(azidomethyl)-substituted p-xylene-α,α'-dibenzylammonium dication and two dibenzo-24-crown-8 rings - and a [3]rotaxane derived from it - by two dipolar cycloadditions of the azidomethyl groups with di-t-butyl acetylenedicarboxylate - are described. The (super)structures are remarkably similar in their geometries and packing.",

author = "Ashton, {Peter R.} and Glink, {Peter T.} and Stoddart, {J. Fraser} and Stephan Menzer and Tasker, {Peter A.} and White, {Andrew J P} and Williams, {David J.}",

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T1 - The solid state structures of a [3]rotaxane and its [3]pseudorotaxane precursor

AU - Ashton, Peter R.

AU - Glink, Peter T.

AU - Stoddart, J. Fraser

AU - Menzer, Stephan

AU - Tasker, Peter A.

AU - White, Andrew J P

AU - Williams, David J.

PY - 1996/8/19

Y1 - 1996/8/19

N2 - The solid state structures of a [3]pseudorotaxane - formed from a bis(azidomethyl)-substituted p-xylene-α,α'-dibenzylammonium dication and two dibenzo-24-crown-8 rings - and a [3]rotaxane derived from it - by two dipolar cycloadditions of the azidomethyl groups with di-t-butyl acetylenedicarboxylate - are described. The (super)structures are remarkably similar in their geometries and packing.

AB - The solid state structures of a [3]pseudorotaxane - formed from a bis(azidomethyl)-substituted p-xylene-α,α'-dibenzylammonium dication and two dibenzo-24-crown-8 rings - and a [3]rotaxane derived from it - by two dipolar cycloadditions of the azidomethyl groups with di-t-butyl acetylenedicarboxylate - are described. The (super)structures are remarkably similar in their geometries and packing.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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