The structure-directing properties of [VOF5]2-

Margaret E. Welk; Alexander J. Norquist; Charlotte L. Stern; Kenneth R. Poeppelmeier

doi:10.1021/ic000416d

The structure-directing properties of [VOF₅]^2-

Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, Kenneth R. Poeppelmeier^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

All of the Group 5 anions [MOF₅]^2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF₅]^2- and [TaOF₅]^2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF₅]^2-. The structure-directing properties of [VOF₅]^2- more closely resemble those of the Group 6 anion [MoO₂F₄]^2-.

Original language	English (US)
Pages (from-to)	3946-3947
Number of pages	2
Journal	Inorganic chemistry
Volume	39
Issue number	18
DOIs	https://doi.org/10.1021/ic000416d
State	Published - Sep 4 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "The structure-directing properties of [VOF5]2-",

abstract = "All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.",

author = "Welk, {Margaret E.} and Norquist, {Alexander J.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R.}",

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T1 - The structure-directing properties of [VOF5]2-

AU - Welk, Margaret E.

AU - Norquist, Alexander J.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R.

PY - 2000/9/4

Y1 - 2000/9/4

N2 - All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.

AB - All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-.

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