The structure of oxygen fluoride

James A. Ibers; Verner Schomaker

doi:10.1021/j150508a023

The structure of oxygen fluoride

James A. Ibers^*, Verner Schomaker

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A bond angle of 103.8 ± 1.5° and a bond length of 1.413 ± 0.019 Å. have been found for oxygen fluoride by the method of electron diffraction. Combining our data with the spectroscopic rotational constant reported by Bernstein and Powling,² we arrive at a bond angle of 103.2° and a bond length of 1.418 Å. as most probable values. Special attention was given the problem of weighting the measured ring diameters, and a simple adjustment was finally adopted which may prove useful in other electron diffraction work of this kind.

Original language	English (US)
Pages (from-to)	699-701
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	57
Issue number	7
DOIs	https://doi.org/10.1021/j150508a023
State	Published - Jan 1 1953

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

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title = "The structure of oxygen fluoride",

abstract = "A bond angle of 103.8 ± 1.5° and a bond length of 1.413 ± 0.019 {\AA}. have been found for oxygen fluoride by the method of electron diffraction. Combining our data with the spectroscopic rotational constant reported by Bernstein and Powling,2 we arrive at a bond angle of 103.2° and a bond length of 1.418 {\AA}. as most probable values. Special attention was given the problem of weighting the measured ring diameters, and a simple adjustment was finally adopted which may prove useful in other electron diffraction work of this kind.",

author = "Ibers, {James A.} and Verner Schomaker",

year = "1953",

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AU - Ibers, James A.

AU - Schomaker, Verner

PY - 1953/1/1

Y1 - 1953/1/1

N2 - A bond angle of 103.8 ± 1.5° and a bond length of 1.413 ± 0.019 Å. have been found for oxygen fluoride by the method of electron diffraction. Combining our data with the spectroscopic rotational constant reported by Bernstein and Powling,2 we arrive at a bond angle of 103.2° and a bond length of 1.418 Å. as most probable values. Special attention was given the problem of weighting the measured ring diameters, and a simple adjustment was finally adopted which may prove useful in other electron diffraction work of this kind.

AB - A bond angle of 103.8 ± 1.5° and a bond length of 1.413 ± 0.019 Å. have been found for oxygen fluoride by the method of electron diffraction. Combining our data with the spectroscopic rotational constant reported by Bernstein and Powling,2 we arrive at a bond angle of 103.2° and a bond length of 1.418 Å. as most probable values. Special attention was given the problem of weighting the measured ring diameters, and a simple adjustment was finally adopted which may prove useful in other electron diffraction work of this kind.

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DO - 10.1021/j150508a023

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JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

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The structure of oxygen fluoride

Abstract

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