The structure of the new quaternary layered material [Co1.5Pt0.5]Ta6PtSe16

Steven A. Sunshine*, James A Ibers

*Corresponding author for this work

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

The new quaternary layered compound [Co1.5Pt0.5]Ta6PtSe16 has been prepared and structurally characterized. This compound crystallizes in the monoclinic system (C32h- C2 m, a = 13.089(18), b = 3.425(3), c = 24.436(25) Å, and β = 104.9(1)°) with two formula units in the cell. The structure contains Ta atoms in both trigonal prismatic and octahedral sites, Co atoms in a square-pyramidal environment, and Pt atoms with both square-pyramidal and square-planar coordination. This compound is related to the Co2Ta4PdSe12 structural type where an additional TaSe2 unit has been added to the chains of metal atoms.

Original languageEnglish (US)
Pages (from-to)219-223
Number of pages5
JournalJournal of Solid State Chemistry
Volume69
Issue number2
DOIs
StatePublished - Jan 1 1987

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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