The syntheses and complexing properties of oxo-12-crown-3 and oxo-18-crown-5

Geoffrey D. Beresford, J. Fraser Stoddart*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

Derivatives of 12-crown-4 and 18-crown-6 in which one of the ethereal oxygens is replaced by a CO group have been synthesised and their complexing abilities towards both metal and organic cations have been assessed. Variable temperature 1H decoupled 13C n.m.r. spectroscopy reveals the presence of anisometric species in solution when a 1:1 complex is formed between oxo-18-crown-5 and (S)-PhCHMeNH3 +ClO4.

Original languageEnglish (US)
Pages (from-to)867-870
Number of pages4
JournalTetrahedron Letters
Volume21
Issue number9
DOIs
StatePublished - Jan 1 1980

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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