The two-state model applied to high pressure mobility results for 2,2,4-trimethylpentane

Y. A. Berlin; R. A. Holroyd

doi:10.1063/1.459070

The two-state model applied to high pressure mobility results for 2,2,4-trimethylpentane

Y. A. Berlin^*, R. A. Holroyd

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The behavior of the electron mobility in 2,2,4-trimethylpentane at high pressure is analyzed in the framework of the two-state model of electron transport. The increase in mobility at 22.5°, as the pressure increases, is shown to be correlated with an increase in μ_F, the free state mobility. The probability of localization first decreases slightly then increases slightly with pressure. Although both the conduction band energy V₀ and the trapped state energy E_t increase with pressure, the difference V₀ - E_t is shown to remain constant.

Original language	English (US)
Pages (from-to)	1939-1941
Number of pages	3
Journal	The Journal of Chemical Physics
Volume	93
Issue number	3
DOIs	https://doi.org/10.1063/1.459070
State	Published - Jan 1 1990

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The behavior of the electron mobility in 2,2,4-trimethylpentane at high pressure is analyzed in the framework of the two-state model of electron transport. The increase in mobility at 22.5°, as the pressure increases, is shown to be correlated with an increase in μF, the free state mobility. The probability of localization first decreases slightly then increases slightly with pressure. Although both the conduction band energy V0 and the trapped state energy Et increase with pressure, the difference V0 - Et is shown to remain constant.",

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N2 - The behavior of the electron mobility in 2,2,4-trimethylpentane at high pressure is analyzed in the framework of the two-state model of electron transport. The increase in mobility at 22.5°, as the pressure increases, is shown to be correlated with an increase in μF, the free state mobility. The probability of localization first decreases slightly then increases slightly with pressure. Although both the conduction band energy V0 and the trapped state energy Et increase with pressure, the difference V0 - Et is shown to remain constant.

AB - The behavior of the electron mobility in 2,2,4-trimethylpentane at high pressure is analyzed in the framework of the two-state model of electron transport. The increase in mobility at 22.5°, as the pressure increases, is shown to be correlated with an increase in μF, the free state mobility. The probability of localization first decreases slightly then increases slightly with pressure. Although both the conduction band energy V0 and the trapped state energy Et increase with pressure, the difference V0 - Et is shown to remain constant.

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The two-state model applied to high pressure mobility results for 2,2,4-trimethylpentane

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