The x-ray crystal structure of a 1:1 adduct between α-cyclodextrin and cyclobutane-1,1-dicarboxylatodiammineplatinum(II)

David R. Alston; Alexandra M Z Slawin; J. Fraser Stoddart; David J. Williams

doi:10.1039/C39850001602

The x-ray crystal structure of a 1:1 adduct between α-cyclodextrin and cyclobutane-1,1-dicarboxylatodiammineplatinum(II)

David R. Alston^*, Alexandra M Z Slawin, J. Fraser Stoddart, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

In the second sphere co-ordination of a cyclobutane-1,1- dicarboxylatodiammineplatinum(II) by α-cyclodextrin, stabilisation of the crystalline adduct is achieved by the cyclobutane ring of the guest penetrating into the cavity of the host and the ammine ligands on the guest participating in the formation of two (N-H··O) hydrogen bonds with secondary hydroxy groups at C(3) on neighbouring α-D-glucopyranosidic units in the host.

Original language	English (US)
Pages (from-to)	1602-1604
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39850001602
State	Published - 1985

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Molecular Medicine

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title = "The x-ray crystal structure of a 1:1 adduct between α-cyclodextrin and cyclobutane-1,1-dicarboxylatodiammineplatinum(II)",

abstract = "In the second sphere co-ordination of a cyclobutane-1,1- dicarboxylatodiammineplatinum(II) by α-cyclodextrin, stabilisation of the crystalline adduct is achieved by the cyclobutane ring of the guest penetrating into the cavity of the host and the ammine ligands on the guest participating in the formation of two (N-H··O) hydrogen bonds with secondary hydroxy groups at C(3) on neighbouring α-D-glucopyranosidic units in the host.",

author = "Alston, {David R.} and Slawin, {Alexandra M Z} and Stoddart, {J. Fraser} and Williams, {David J.}",

year = "1985",

doi = "10.1039/C39850001602",

language = "English (US)",

pages = "1602--1604",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "22",

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T1 - The x-ray crystal structure of a 1:1 adduct between α-cyclodextrin and cyclobutane-1,1-dicarboxylatodiammineplatinum(II)

AU - Alston, David R.

AU - Slawin, Alexandra M Z

AU - Stoddart, J. Fraser

AU - Williams, David J.

PY - 1985

Y1 - 1985

N2 - In the second sphere co-ordination of a cyclobutane-1,1- dicarboxylatodiammineplatinum(II) by α-cyclodextrin, stabilisation of the crystalline adduct is achieved by the cyclobutane ring of the guest penetrating into the cavity of the host and the ammine ligands on the guest participating in the formation of two (N-H··O) hydrogen bonds with secondary hydroxy groups at C(3) on neighbouring α-D-glucopyranosidic units in the host.

AB - In the second sphere co-ordination of a cyclobutane-1,1- dicarboxylatodiammineplatinum(II) by α-cyclodextrin, stabilisation of the crystalline adduct is achieved by the cyclobutane ring of the guest penetrating into the cavity of the host and the ammine ligands on the guest participating in the formation of two (N-H··O) hydrogen bonds with secondary hydroxy groups at C(3) on neighbouring α-D-glucopyranosidic units in the host.

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U2 - 10.1039/C39850001602

DO - 10.1039/C39850001602

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

The x-ray crystal structure of a 1:1 adduct between α-cyclodextrin and cyclobutane-1,1-dicarboxylatodiammineplatinum(II)

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