The x-ray crystal structure of a 1:1 adduct between α-cyclodextrin and cyclobutane-1,1-dicarboxylatodiammineplatinum(II)

David R. Alston*, Alexandra M Z Slawin, J. Fraser Stoddart, David J. Williams

*Corresponding author for this work

Research output: Contribution to journalArticle

47 Scopus citations

Abstract

In the second sphere co-ordination of a cyclobutane-1,1- dicarboxylatodiammineplatinum(II) by α-cyclodextrin, stabilisation of the crystalline adduct is achieved by the cyclobutane ring of the guest penetrating into the cavity of the host and the ammine ligands on the guest participating in the formation of two (N-H··O) hydrogen bonds with secondary hydroxy groups at C(3) on neighbouring α-D-glucopyranosidic units in the host.

Original languageEnglish (US)
Pages (from-to)1602-1604
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
DOIs
StatePublished - 1985

ASJC Scopus subject areas

  • Molecular Medicine

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