Theory of translational-vibrational energy transfer for reactive collisions

Sighart F. Fischer*, Mark A. Ratner

*Corresponding author for this work

Research output: Contribution to journalArticle

41 Scopus citations

Abstract

A quantum mechanical theory for polyatomic molecules undergoing bimolecular reactions is presented which allows prediction of the vibrational excitation of the products as a function of (a) the incident translational energy, (b) the curvature of the reaction path, (c) the frequency changes for degrees of freedom perpendicular to the reaction coordinate, and (d) the position of the saddle point of the potential hypersurface.

Original languageEnglish (US)
Pages (from-to)2769-2776
Number of pages8
JournalThe Journal of Chemical Physics
Volume57
Issue number7
DOIs
StatePublished - Jan 1 1972

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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