Thermal effects on energetics and dynamics in water cluster anions (H 2O) n -

Ryan M. Young, Margaret A. Yandell, Sarah B. King, Daniel M. Neumark*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    19 Scopus citations

    Abstract

    The electron binding energies and relaxation dynamics of water cluster anions (H 2O) n - (11 ≤ n ≤ 80) formed in co-expansions with neon were investigated using one-photon and time-resolved photoelectron imaging. Unlike previous experiments with argon, water cluster anions exhibit only one isomer class, the tightly bound isomer I with approximately the same binding energy as clusters formed in argon. This result, along with a decrease in the internal conversion lifetime of excited (H 2O) n - (25 ≤ n ≤ 40), indicates that clusters are vibrationally warmer when formed in neon. Over the ranges studied, the vertical detachment energies and lifetimes appear to converge to previously reported values.

    Original languageEnglish (US)
    Article number094304
    JournalJournal of Chemical Physics
    Volume136
    Issue number9
    DOIs
    StatePublished - Mar 7 2012

    ASJC Scopus subject areas

    • Physics and Astronomy(all)
    • Physical and Theoretical Chemistry

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