Thermal stability of Mg2Si0.4Sn0.6 in inert gases and atomic-layer-deposited Al2O3 thin film as a protective coating

Libin Zhang*, Xi Chen, Yinglu Tang, Li Shi, G. Jeffrey Snyder, John B. Goodenough, Jianshi Zhou

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations


Mg2Si1−xSnx solid solutions are promising thermoelectric materials to be applied in vehicle waste-heat recovery. Their thermal stability issue, however, needs to be addressed before the materials can be applied in practical thermoelectric devices. In this work, we studied the crystal structure and chemical composition of Mg2Si1−xSnx in inert gas atmosphere up to 823 K. We found that the sample was oxidized even in high-purity inert gases. Although no obvious structural change has been found in the slightly oxidized sample, carrier concentration decreased significantly since oxidation creates Mg vacancies in the lattice. We demonstrated that an atomic-layer deposited Al2O3 coating can effectively protect Mg2Si1−xSnx from oxidation in inert gases and even in air. In addition, this Al2O3 thin film also provides in situ protection to the Sb-doped Mg2Si1−xSnx samples during the laser-flash measurement and therefore eliminates the measurement error that occurs in uncoated samples as a result of sample oxidation and graphite exfoliation issues.

Original languageEnglish (US)
Pages (from-to)17726-17731
Number of pages6
JournalJournal of Materials Chemistry A
Issue number45
StatePublished - Jan 1 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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