Thermally and electrochemically controllable self-complexing molecular switches

Yi Liu, Amar H. Flood, J. Fraser Stoddart*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

117 Scopus citations

Abstract

Self-complexing molecular systems are obtained when an arm component (a π-donor) is covalently linked to a preformed macrocycle (a π-acceptor). The resulting self-complexing compounds are not only attractive in relation to their topology, but also for their potential to undergo reversible movements, i.e., the arm can be driven out of or into the cavity of the linked macrocycle in response to temperature or applied voltage. These structurally sensitive changes render them potential thermosensors or electroswitches.

Original languageEnglish (US)
Pages (from-to)9150-9151
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number30
DOIs
StatePublished - Aug 4 2004

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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