Thermodynamic Synthesis of Rotaxanes by Imine Exchange

Stuart J. Rowan; J. Fraser Stoddart

doi:10.1021/ol991047w

Thermodynamic Synthesis of Rotaxanes by Imine Exchange

Stuart J. Rowan, J. Fraser Stoddart^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

(Matrix Presented) By utilizing the dynamic nature of imine bonds, it is possible to construct [2]rotaxanes from a ring and a preformed dumbbell under thermodynamic control. These dynamic [2]rotaxanes, which exhibit reversible supramolecular-like behavior in the presence of appropriate catalysts, can be "fixed" by reduction of their imine bonds.

Original language	English (US)
Pages (from-to)	1913-1916
Number of pages	4
Journal	Organic Letters
Volume	1
Issue number	12
DOIs	https://doi.org/10.1021/ol991047w
State	Published - Dec 16 1999

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol991047w

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title = "Thermodynamic Synthesis of Rotaxanes by Imine Exchange",

abstract = "(Matrix Presented) By utilizing the dynamic nature of imine bonds, it is possible to construct [2]rotaxanes from a ring and a preformed dumbbell under thermodynamic control. These dynamic [2]rotaxanes, which exhibit reversible supramolecular-like behavior in the presence of appropriate catalysts, can be {"}fixed{"} by reduction of their imine bonds.",

author = "Rowan, {Stuart J.} and Stoddart, {J. Fraser}",

year = "1999",

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day = "16",

doi = "10.1021/ol991047w",

language = "English (US)",

volume = "1",

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journal = "Organic Letters",

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publisher = "American Chemical Society",

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T1 - Thermodynamic Synthesis of Rotaxanes by Imine Exchange

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AU - Stoddart, J. Fraser

PY - 1999/12/16

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N2 - (Matrix Presented) By utilizing the dynamic nature of imine bonds, it is possible to construct [2]rotaxanes from a ring and a preformed dumbbell under thermodynamic control. These dynamic [2]rotaxanes, which exhibit reversible supramolecular-like behavior in the presence of appropriate catalysts, can be "fixed" by reduction of their imine bonds.

AB - (Matrix Presented) By utilizing the dynamic nature of imine bonds, it is possible to construct [2]rotaxanes from a ring and a preformed dumbbell under thermodynamic control. These dynamic [2]rotaxanes, which exhibit reversible supramolecular-like behavior in the presence of appropriate catalysts, can be "fixed" by reduction of their imine bonds.

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U2 - 10.1021/ol991047w

DO - 10.1021/ol991047w

M3 - Article

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JO - Organic Letters

JF - Organic Letters

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ER -

Thermodynamic Synthesis of Rotaxanes by Imine Exchange

Abstract

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