Thermoreversible crosslinking of polyelectrolyte chains

A. V. Ermoshkin; A. N. Kudlay; M. Olvera De La Cruz

doi:10.1063/1.1753573

Thermoreversible crosslinking of polyelectrolyte chains

A. V. Ermoshkin^*, A. N. Kudlay, M. Olvera De La Cruz

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The thermoreversible crosslinking effects such as gelation transition of polyelectrolyte chains were investigated within the Flory model of ideal association. The electrostatic interaction between charges were considered using a generalized random phase approximation (RPA). An infinitely large polymer network was formed at certain concentration of linking agents. The results show that gelation transitions underwent phase segregation only within region bound by gelation curves.

Original language	English (US)
Pages (from-to)	11930-11940
Number of pages	11
Journal	Journal of Chemical Physics
Volume	120
Issue number	24
DOIs	https://doi.org/10.1063/1.1753573
State	Published - Jun 22 2004

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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abstract = "The thermoreversible crosslinking effects such as gelation transition of polyelectrolyte chains were investigated within the Flory model of ideal association. The electrostatic interaction between charges were considered using a generalized random phase approximation (RPA). An infinitely large polymer network was formed at certain concentration of linking agents. The results show that gelation transitions underwent phase segregation only within region bound by gelation curves.",

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