Thermorheologically complex behavior of multi-phase viscoelastic materials

L. C. Brinson*, W. G. Knauss

*Corresponding author for this work

Research output: Contribution to journalArticle

33 Scopus citations

Abstract

The dynamic correspondence principle of viscoelasticity is used to study the nature of time-temperature behavior of multi-phase composites by means of finite element computation. The composite considered contains viscoelastic inclusions embedded in a viscoelastic matrix. Each phase of the composite is considered to be thermorheologically simple, but the resulting mechanical properties of the composite are thermorheologically complex. The deviation of the composite moduli from thermorheologically simple behavior of the matrix material is shown to occur at frequencies and temperatures where the glass-to-rubber transition of the included phases are reached. Properties of a styrene-butadiene-styrene (SBS) block copolymer are investigated based on the individual phase properties of polystyrene and polybutadiene. To achieve congruence of the results with experimental data, it is necessary to consider a transition phase of properties "intermediate" to those of polystyrene and polybutadiene. Using accurate physical information on the individual phase properties and on the interphase region, it is possible to predict properties of multiphase composites. Although detailed a priori knowledge of such an interphase is usually lacking, it is shown that the computational procedure presented here together with an extended range of test frequencies will aid in estimating the properties of the phase in question.

Original languageEnglish (US)
Pages (from-to)859-880
Number of pages22
JournalJournal of the Mechanics and Physics of Solids
Volume39
Issue number7
DOIs
StatePublished - 1991

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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