TY - JOUR
T1 - Thiamacrocyclic chemistry
T2 - Synthesis of a novel oxadithiacrown and its copper iodide complex
AU - Ashton, Peter R.
AU - Burns, Andrew L.
AU - Claessens, Christian G.
AU - Shimizu, George K H
AU - Small, Karen
AU - Fraser Stoddart, J.
AU - White, Andrew J P
AU - Williams, David J.
PY - 1997
Y1 - 1997
N2 - A mixed oxa-thia macrocycle incorporating a rigid 'horseshoe-shaped' aromatic moiety, 1,1 l,21-trioxa-8,14-dithia[2,9,2]paracyclophane, L, has been synthesised. The molecular structures of L and of its copper iodide complex have been determined by single-crystal X-ray diffraction methods. There are two independent conformations observed in the solid state for the macrocycle, L. Its copper iodide complex [Cu2I2(L)]-1.25MeCN, crystallises, in a 2:1 metal:crown ratio, as a one-dimensional infinite array of cubane-like units consisting of four copper atoms, four iodine atoms and four sulfur atoms from four different macrocycles.
AB - A mixed oxa-thia macrocycle incorporating a rigid 'horseshoe-shaped' aromatic moiety, 1,1 l,21-trioxa-8,14-dithia[2,9,2]paracyclophane, L, has been synthesised. The molecular structures of L and of its copper iodide complex have been determined by single-crystal X-ray diffraction methods. There are two independent conformations observed in the solid state for the macrocycle, L. Its copper iodide complex [Cu2I2(L)]-1.25MeCN, crystallises, in a 2:1 metal:crown ratio, as a one-dimensional infinite array of cubane-like units consisting of four copper atoms, four iodine atoms and four sulfur atoms from four different macrocycles.
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U2 - 10.1039/a608218a
DO - 10.1039/a608218a
M3 - Article
AN - SCOPUS:33751133983
SN - 0300-9246
SP - 1493
EP - 1496
JO - Journal of the Chemical Society - Dalton Transactions
JF - Journal of the Chemical Society - Dalton Transactions
IS - 9
ER -