Thickening Mechanisms of Polyisobutylene in Polyalphaolefin

Michelle Len, Uma Shantini Ramasamy, Seth Lichter, Ashlie Martini*

*Corresponding author for this work

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

Molecular dynamics simulations are used to study the effect of polyisobutylene polymer on the viscosity of polyalphaolefin base oil. The Newtonian viscosities of the solution calculated from simulations at 40 and 100 °C agree with rheometer measurements. The simulations are used to investigate three possible mechanisms by which the polymer may increase solution viscosity. The results indicate that neither (1) coil expansion nor (2) polymer–polymer association underlie viscosity enhancement in the case studied here. Measurements of solvent reorientation close to the additive molecule suggest that (3) modification of the solvent by the additive molecule contributes to viscosity enhancement.

Original languageEnglish (US)
Article number5
JournalTribology Letters
Volume66
Issue number1
DOIs
StatePublished - Mar 1 2018

Keywords

  • Polyisobutylene
  • Polymer association
  • Radius of gyration
  • Viscosity modifiers
  • Viscosity–temperature

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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