Three-dimensional frameworks of cubic (NH4)5Ga 4SbS10, (NH4)4Ga4SbS 9(OH) · H2O, and (NH4) 3Ga4SbS9(OH2) · 2H 2O

Joshua L. Mertz; Nan Ding; Mercouri G. Kanatzidis

doi:10.1021/ic901927r

Three-dimensional frameworks of cubic (NH₄)₅Ga ₄SbS₁₀, (NH₄)₄Ga₄SbS ₉(OH) · H₂O, and (NH₄) ₃Ga₄SbS₉(OH₂) · 2H ₂O

Joshua L. Mertz, Nan Ding, Mercouri G. Kanatzidis

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Three new isostructural open-framework sulfides, (NH₄) ₅Ga₄-SbS₁₀ (1), (NH₄) ₄Ga₄SbS₉(OH) · H₂O (2a), and (NH₄)₃Ga₄SbS₉-(H₂O) · 2H₂O (2b), were synthesized under basic hydrothermal conditions using ammonium hydroxide as the structure-directing agent. The structures feature a three-dimensional open framework comprised of adamantane [Ga₄Q₁₀]^8- clusters linked with Sb³⁺ centers. The compounds are wide gap semiconductors, crystallize in the chiral space group P2₁3, and represent a new structure type. They exhibit nonlinear optical properties.

Original language	English (US)
Pages (from-to)	10898-10900
Number of pages	3
Journal	Inorganic chemistry
Volume	48
Issue number	23
DOIs	https://doi.org/10.1021/ic901927r
State	Published - 2009

Funding

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

Access to Document

10.1021/ic901927r

Cite this

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title = "Three-dimensional frameworks of cubic (NH4)5Ga 4SbS10, (NH4)4Ga4SbS 9(OH) · H2O, and (NH4) 3Ga4SbS9(OH2) · 2H 2O",

abstract = "Three new isostructural open-framework sulfides, (NH4) 5Ga4-SbS10 (1), (NH4) 4Ga4SbS9(OH) · H2O (2a), and (NH4)3Ga4SbS9-(H2O) · 2H2O (2b), were synthesized under basic hydrothermal conditions using ammonium hydroxide as the structure-directing agent. The structures feature a three-dimensional open framework comprised of adamantane [Ga4Q10]8- clusters linked with Sb3+ centers. The compounds are wide gap semiconductors, crystallize in the chiral space group P213, and represent a new structure type. They exhibit nonlinear optical properties.",

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T1 - Three-dimensional frameworks of cubic (NH4)5Ga 4SbS10, (NH4)4Ga4SbS 9(OH) · H2O, and (NH4) 3Ga4SbS9(OH2) · 2H 2O

AU - Mertz, Joshua L.

AU - Ding, Nan

AU - Kanatzidis, Mercouri G.

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AB - Three new isostructural open-framework sulfides, (NH4) 5Ga4-SbS10 (1), (NH4) 4Ga4SbS9(OH) · H2O (2a), and (NH4)3Ga4SbS9-(H2O) · 2H2O (2b), were synthesized under basic hydrothermal conditions using ammonium hydroxide as the structure-directing agent. The structures feature a three-dimensional open framework comprised of adamantane [Ga4Q10]8- clusters linked with Sb3+ centers. The compounds are wide gap semiconductors, crystallize in the chiral space group P213, and represent a new structure type. They exhibit nonlinear optical properties.

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