Abstract
We discuss the application of photoelectron angular distributions as a probe of time-evolving rovibrational wavepackets. A physical picture is drawn of the mechanism through which rotation-vibration coupling mechanisms are reflected in the time-dependent photoionization asymmetry parameters. The effects of complicating features that may obscure the interpretation of time-resolved photoelectron spectroscopies, including the field intensity and the inherent complexity of ionization processes are examined.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 99-108 |
| Number of pages | 10 |
| Journal | Journal of Electron Spectroscopy and Related Phenomena |
| Volume | 108 |
| Issue number | 1 |
| DOIs | |
| State | Published - Jul 2000 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Radiation
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
- Spectroscopy
- Physical and Theoretical Chemistry