TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

X. Zhou; Tobin Jay Marks; Stephen Howard Carr

TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

X. Zhou^*, Tobin Jay Marks, Stephen Howard Carr

^*Corresponding author for this work

Research output: Contribution to conference › Paper › peer-review

3 Scopus citations

Abstract

The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

Original language	English (US)
Pages	651-654
Number of pages	4
State	Published - Dec 1 1984

ASJC Scopus subject areas

Engineering(all)

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title = "TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.",

abstract = "The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.",

author = "X. Zhou and Marks, {Tobin Jay} and Carr, {Stephen Howard}",

year = "1984",

month = dec,

day = "1",

language = "English (US)",

pages = "651--654",

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T1 - TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

AU - Zhou, X.

AU - Marks, Tobin Jay

AU - Carr, Stephen Howard

PY - 1984/12/1

Y1 - 1984/12/1

N2 - The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

AB - The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

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M3 - Paper

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ER -

TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

Abstract

ASJC Scopus subject areas

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