TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

X. Zhou; Tobin Jay Marks; Stephen Howard Carr

TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.

X. Zhou^*, Tobin Jay Marks, Stephen Howard Carr

^*Corresponding author for this work

Research output: Contribution to conference › Paper

3 Scopus citations

Abstract

The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

Original language	English (US)
Pages	651-654
Number of pages	4
State	Published - Dec 1 1984

ASJC Scopus subject areas

Engineering(all)

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Zhou, X., Marks, T. J., & Carr, S. H. (1984). TOPOTACTIC POLYMERIZATION MECHANISM OF PHTHALOCYANINATOGERMANIUM DIHYDROXIDE IN THE SOLID STATE.. 651-654.

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abstract = "The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.",

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AU - Carr, Stephen Howard

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N2 - The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

AB - The cofacially linked Group IV poly (phthalocyaninatometalloxane) macromolecules, left bracket M(Pc)O right bracket //n, M equals Si, Ge, Sn are precursors for a broad new class of environmentally stable and processable electrically conductive polymers. This contribution presents mechanistic information on the Ge(Pc)(OH)//2 polymerization by TEM (transmission electron microscopy) and DSC (differential scanning calorimetry). It reports on direct imaging of the left bracket Ge(Pc)O right bracket //n lattice (the first for a conductive polymer), new structural information on Ge(Pc)(OH)//2 evidence for the topotacticity of the polymerization process, and a reasonable mechanism for the polymerization.

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