Toward the Mott state with magnetic cluster formation in heavily Cu-doped NaFe1-xCuxAs

Yizhou Xin*, Ingrid Stolt, Jeongseop A. Lee, Yu Song, Pengcheng Dai, W. P. Halperin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Recent neutron-scattering measurements indicate that NaFe1-xCuxAs forms an antiferromagnetic stripe phase near x≈0.5 in a Mott insulating state. This copper concentration is well in excess of that required for superconductivity, x<0.04. We have investigated the development of magnetism in this compound by using Na23 nuclear magnetic resonance (NMR) spectra and spin-lattice relaxation measurements performed on single crystals (x=0.13, 0.18, 0.24, and 0.39). We find multiple inequivalent Na sites, each of which is associated with a different number of nearest-neighbor Fe sites occupied by a Cu dopant. We show that the distribution of Cu substituted for Fe is random in-plane for low concentrations (x=0.13 and 0.18) but deviates from this with increasing Cu doping. As is characteristic of many pnictide compounds, there is a spin pseudogap that increases in magnitude with dopant concentration. This is correlated with a corresponding increase in orbital NMR frequency shift, indicating a change in valence from Cu2+ to a Cu1+ state as x exceeds 0.18, concomitant with the change of Fe2+ to Fe3+ resulting in the formation of magnetic clusters. However, for x≤0.39 there is no evidence of long-range static magnetic order.

Original languageEnglish (US)
Article number155114
JournalPhysical Review B
Volume99
Issue number15
DOIs
StatePublished - Apr 8 2019

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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