Towards disentangling coupled electronic-vibrational dynamics in ultrafast non-adiabatic processes

V. Blanchet, S. Lochbrunner, M. Schmitt, J. P. Shaffer, J. J. Larsen, M. Z. Zgierski, T. Seideman, A. Stolow*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

36 Scopus citations


Femtosecond time-resolved photoelectron spectroscopy is emerging as a new technique for investigating polyatomic excited state dynamics. Due to the sensitivity of photoelectron spectroscopy to both electronic configurations and vibrational dynamics, it is well suited to the study of non-adiabatic processes such as internal conversion, which often occur on sub-picosecond time scales. We discuss the technical requirements for such experiments, including lasers systems, energy- and angle-resolved photoelectron spectrometers and new detectors for coincidence experiments. We present a few examples of these methods applied to problems in diatomic wavepacket dynamics and ultrafast non-adiabatic processes in polyatomic molecules.

Original languageEnglish (US)
Pages (from-to)33-48
Number of pages16
JournalFaraday Discussions
StatePublished - 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry


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