Trans-bis(hexafluoroantimonato)(phthalocyaninato)copper(II)

Anna S. Gardberg; James A Ibers

doi:10.1107/S0108270101001561

Trans-bis(hexafluoroantimonato)(phthalocyaninato)copper(II)

Anna S. Gardberg, James A Ibers

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The title compound, trans-bis(hexafluoroantimonato-F)(phthalocyaninato -K⁴N^29,30,31,32)copper(II), [Cu(SbF₆)₂(C₃₂H₁₆N₈)] or Cu(pc)(SbF₆)₂ (pc is phthalocyaninate), comprises a six-coordinate Cu atom, lying on an inversion center, bonded to four N atoms of a phthalocyanine ring and to F atoms of two trans SbF₆^- groups. The compound is presumed to consist of a Cu^II center and a doubly oxidized phthalocyanine ring, by analogy with Cu(pc)(ReO₄)₂.

Original language	English (US)
Pages (from-to)	528-529
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	5
DOIs	https://doi.org/10.1107/S0108270101001561
State	Published - Jan 1 2001

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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title = "Trans-bis(hexafluoroantimonato)(phthalocyaninato)copper(II)",

abstract = "The title compound, trans-bis(hexafluoroantimonato-F)(phthalocyaninato -K4N29,30,31,32)copper(II), [Cu(SbF6)2(C32H16N8)] or Cu(pc)(SbF6)2 (pc is phthalocyaninate), comprises a six-coordinate Cu atom, lying on an inversion center, bonded to four N atoms of a phthalocyanine ring and to F atoms of two trans SbF6- groups. The compound is presumed to consist of a CuII center and a doubly oxidized phthalocyanine ring, by analogy with Cu(pc)(ReO4)2.",

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AU - Gardberg, Anna S.

AU - Ibers, James A

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N2 - The title compound, trans-bis(hexafluoroantimonato-F)(phthalocyaninato -K4N29,30,31,32)copper(II), [Cu(SbF6)2(C32H16N8)] or Cu(pc)(SbF6)2 (pc is phthalocyaninate), comprises a six-coordinate Cu atom, lying on an inversion center, bonded to four N atoms of a phthalocyanine ring and to F atoms of two trans SbF6- groups. The compound is presumed to consist of a CuII center and a doubly oxidized phthalocyanine ring, by analogy with Cu(pc)(ReO4)2.

AB - The title compound, trans-bis(hexafluoroantimonato-F)(phthalocyaninato -K4N29,30,31,32)copper(II), [Cu(SbF6)2(C32H16N8)] or Cu(pc)(SbF6)2 (pc is phthalocyaninate), comprises a six-coordinate Cu atom, lying on an inversion center, bonded to four N atoms of a phthalocyanine ring and to F atoms of two trans SbF6- groups. The compound is presumed to consist of a CuII center and a doubly oxidized phthalocyanine ring, by analogy with Cu(pc)(ReO4)2.

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Trans-bis(hexafluoroantimonato)(phthalocyaninato)copper(II)

Abstract

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