Transformation of an [Fe(η2-N2H 3)]+ species to π-delocalized [Fe2(μ- N2H2)]2+/+ complexes

Caroline T. Saouma, R. Adam Kinney, Brian M. Hoffman, Jonas C. Peters

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

Diiron diazenes: A monomeric Fe(η22-N 2H3) species has been prepared, and exposure to oxygen yields a diiron complex that features five-coordinate iron centers and an activated bridging diazene ligand (see picture; C gray, N blue, Fe black, P red, O green). Structural, theoretical, and spectroscopic data for the redox pair [Fe2(μ-N2H2)]2+/+ are consistent with 4-center, 4-electron π-delocalized bonding across the Fe-NH-NH-Fe core that finds analogy in butadiene and the butadiene anion.

Original languageEnglish (US)
Pages (from-to)3446-3449
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number15
DOIs
StatePublished - Apr 4 2011

Keywords

  • ENDOR spectroscopy
  • diazene
  • hydrazido ligand
  • mixed-valence complexes
  • nitrogen fixation

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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