Transmetalation: Routes to metal exchange within metal-organic frameworks

Marianne Lalonde; Wojciech Bury; Olga Karagiaridi; Zachary Brown; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c3ta10784a

Transmetalation: Routes to metal exchange within metal-organic frameworks

Marianne Lalonde, Wojciech Bury, Olga Karagiaridi, Zachary Brown, Joseph T. Hupp^*, Omar K. Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

227 Scopus citations

Abstract

The present work is a critical review of metal exchange (transmetalation) involving metal nodes and metalated struts in metal-organic frameworks. Particular emphasis is given to drawing parallels between different examples of transmetalation in order to understand the influence of coordination environment, solvents, nature of the metals and other variables on the process. We hope that the present review will be of use to those involved in the incorporation of various metal centers to create isostructural MOFs and study their properties.

Original language	English (US)
Pages (from-to)	5453-5468
Number of pages	16
Journal	Journal of Materials Chemistry A
Volume	1
Issue number	18
DOIs	https://doi.org/10.1039/c3ta10784a
State	Published - May 14 2013

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Chemistry(all)
Renewable Energy, Sustainability and the Environment
Materials Science(all)

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10.1039/c3ta10784a

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Transmetalation: Routes to metal exchange within metal-organic frameworks

Abstract

ASJC Scopus subject areas

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