Triple-decker complexes formed via the weak link approach

You Moon Jeon; Jungseok Heo; Aaron M. Brown; Chad A. Mirkin

doi:10.1021/om0602310

Triple-decker complexes formed via the weak link approach

You Moon Jeon, Jungseok Heo, Aaron M. Brown, Chad A. Mirkin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

Original language	English (US)
Pages (from-to)	2729-2732
Number of pages	4
Journal	Organometallics
Volume	25
Issue number	11
DOIs	https://doi.org/10.1021/om0602310
State	Published - May 22 2006

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om0602310

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title = "Triple-decker complexes formed via the weak link approach",

abstract = "Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.",

author = "Jeon, {You Moon} and Jungseok Heo and Brown, {Aaron M.} and Mirkin, {Chad A.}",

year = "2006",

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AU - Jeon, You Moon

AU - Heo, Jungseok

AU - Brown, Aaron M.

AU - Mirkin, Chad A.

PY - 2006/5/22

Y1 - 2006/5/22

N2 - Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

AB - Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

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Triple-decker complexes formed via the weak link approach

Abstract

ASJC Scopus subject areas

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