Triple-decker complexes formed via the weak link approach

You Moon Jeon; Jungseok Heo; Aaron M. Brown; Chad A. Mirkin

doi:10.1021/om0602310

Triple-decker complexes formed via the weak link approach

You Moon Jeon, Jungseok Heo, Aaron M. Brown, Chad A. Mirkin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

Original language	English (US)
Pages (from-to)	2729-2732
Number of pages	4
Journal	Organometallics
Volume	25
Issue number	11
DOIs	https://doi.org/10.1021/om0602310
State	Published - May 22 2006

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.",

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