Triple-decker complexes formed via the weak link approach

You Moon Jeon, Jungseok Heo, Aaron M. Brown, Chad A. Mirkin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

Original languageEnglish (US)
Pages (from-to)2729-2732
Number of pages4
JournalOrganometallics
Volume25
Issue number11
DOIs
StatePublished - May 22 2006

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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