Abstract
Through the weak link approach and a halideinduced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2729-2732 |
| Number of pages | 4 |
| Journal | Organometallics |
| Volume | 25 |
| Issue number | 11 |
| DOIs | |
| State | Published - May 22 2006 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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CCDC 287009: Experimental Crystal Structure Determination
Jeon, Y.-M. (Creator), Heo, J. (Creator), Brown, A. M. (Creator), Mirkin, C. A. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9mncx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9mncx&sid=DataCite
Dataset
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CCDC 287010: Experimental Crystal Structure Determination
Jeon, Y.-M. (Creator), Heo, J. (Creator), Brown, A. M. (Creator), Mirkin, C. A. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9mndy, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9mndy&sid=DataCite
Dataset