Triplet exciton EPR and crystal structure of [TMPD+] 2[Ni(mnt)2]-2

Mufaro J. Hove*, Brian M Hoffman, James A Ibers

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

We report in this paper the results of EPR and x ray diffraction studies on the ionic-radical salt [TMPD+]2[Ni(mnt)2] -2 composed of an organic free radical cation and a diamagnetic transition metal complex ion. This crystal exhibits the triplet exciton EPR spectrum characteristic of an alternating chain of spins. Exciton creation energy is ΔE = 0.240±0.005 eV; triplet spin Hamiltonian parameters are

Original languageEnglish (US)
Pages (from-to)3490-3502
Number of pages13
JournalThe Journal of Chemical Physics
Volume56
Issue number7
DOIs
StatePublished - Jan 1 1972

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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