Tuning Composition and Activity of Cobalt Titanium Oxide Catalysts for the Oxygen Evolution Reaction

Linsey Christine Seitz, Dennis Nordlund, Alessandro Gallo, Thomas F. Jaramillo*

*Corresponding author for this work

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

Understanding catalyst function to improve activity for the oxygen evolution reaction (OER) is key to increasing the overall efficiency of electrochemical water splitting, a promising method for sustainable and clean production of hydrogen. Using a straightforward and scalable sol-gel synthesis, we explore the effects of metal composition in CoxTi1-xOy on electrochemical activity, atomic structure, and electronic state. Physical and electronic characterization reveal that increased amounts of Ti stabilize the 2+ oxidation state of the Co precursor and lead to formation of less active CoO-like catalysts. Conversely, films with Co:Ti ratios of 1:1 or greater result in catalysts with high activity, correlating with greater Co 3+ character, as measured by ex situ XAS for samples as-prepared and after exposure to OER conditions. Additionally, decreasing the Ti content systematically shifts the Co redox potential from approximately 1.5 V vs. RHE with a 1:3 Co:Ti ratio to 1.0 V vs. RHE with no Ti, further evidence that Ti stabilizes Co in a lower oxidation state. Controlling the oxidation state of metals in metal-oxide OER catalysts can have a profound effect on catalytic activity.

Original languageEnglish (US)
Pages (from-to)240-245
Number of pages6
JournalElectrochimica Acta
Volume193
DOIs
StatePublished - Mar 1 2016

Keywords

  • Electrocatalysis
  • Water oxidation
  • X-ray absorption spectroscopy

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

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