Tuning the hydrophobicity of zinc dipyridyl paddlewheel metal-organic frameworks for selective sorption

Mitchell H. Weston; Amelia A. Delaquil; Amy A. Sarjeant; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/cg400342m

Tuning the hydrophobicity of zinc dipyridyl paddlewheel metal-organic frameworks for selective sorption

Mitchell H. Weston, Amelia A. Delaquil, Amy A. Sarjeant, Omar K. Farha^*, Joseph T. Hupp, Sonbinh T. Nguyen

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.

Original language	English (US)
Pages (from-to)	2938-2942
Number of pages	5
Journal	Crystal Growth and Design
Volume	13
Issue number	7
DOIs	https://doi.org/10.1021/cg400342m
State	Published - Jul 3 2013

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/cg400342m

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abstract = "A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.",

author = "Weston, {Mitchell H.} and Delaquil, {Amelia A.} and Sarjeant, {Amy A.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

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AU - Weston, Mitchell H.

AU - Delaquil, Amelia A.

AU - Sarjeant, Amy A.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2013/7/3

Y1 - 2013/7/3

N2 - A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.

AB - A series of isostructural noncatenated, water-stable zinc-based dipyridyl pillared-paddlewheel metal-organic frameworks (MOFs) was synthesized with tunable pore hydrophobicity. Pore hydrophobicity was engendered through dipyridyl ligands decorated with alkyl chains of varying length (methyl to hexyl). The most hydrophobic MOFs exhibited selective sorption of ethanol over water.

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Tuning the hydrophobicity of zinc dipyridyl paddlewheel metal-organic frameworks for selective sorption

Abstract

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CCDC 960320: Experimental Crystal Structure Determination

CCDC 960319: Experimental Crystal Structure Determination

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Tuning the hydrophobicity of zinc dipyridyl paddlewheel metal-organic frameworks for selective sorption

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 960320: Experimental Crystal Structure Determination

CCDC 960319: Experimental Crystal Structure Determination

Cite this