Tuning the Redox Activity of Metal-Organic Frameworks for Enhanced, Selective O₂Binding: Design Rules and Ambient Temperature O₂Chemisorption in a Cobalt-Triazolate Framework

Keyphrases

• Ambient Temperature 100%
• Metal-organic Frameworks (MOFs) 100%
• Design Rules 100%
• Cobalt 100%
• Redox Activity 100%
• Triazolate 100%
• Open Metal Sites 66%
• O2 Adsorption 50%
• Bridging Ligands 33%
• OH Groups 33%
• N2 Adsorption 33%
• Coordinatively Unsaturated Sites 33%
• Small Molecules 16%
• Linker 16%
• Highly Selective 16%
• Screening Method 16%
• Metal Center 16%
• Room Temperature 16%
• Adsorbate 16%
• Screening Study 16%
• Selective Binding 16%
• Electron-donating 16%
• Computational Screening 16%
• H-bonding Interaction 16%
• Benzo 16%
• Physisorption 16%
• Anion Exchange 16%
• Formal Oxidation State 16%
• Adsorbent Materials 16%
• Periodic Density Functional Theory 16%
• O2 Affinity 16%
• Bis-triazole 16%
• O2 Chemisorption 16%
• Tunable Functionalities 16%

Material Science

• Cobalt 100%
• Metal-Organic Framework 100%
• Adsorbate 16%
• Chemisorption 16%
• Density 16%
• Oxidation Reaction 16%