Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Antigoni Douvali; Athanassios C. Tsipis; Svetlana V. Eliseeva; Stéphane Petoud; Giannis S. Papaefstathiou; Christos D. Malliakas; Ioannis Papadas; Gerasimos S. Armatas; Irene Margiolaki; Mercouri G. Kanatzidis; Theodore Lazarides; Manolis J. Manos

doi:10.1002/anie.201410612

Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Antigoni Douvali, Athanassios C. Tsipis, Svetlana V. Eliseeva, Stéphane Petoud, Giannis S. Papaefstathiou, Christos D. Malliakas, Ioannis Papadas, Gerasimos S. Armatas, Irene Margiolaki, Mercouri G. Kanatzidis, Theodore Lazarides, Manolis J. Manos

Chemistry

Research output: Contribution to journal › Article › peer-review

292 Scopus citations

Abstract

The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg²⁺ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

Original language	English (US)
Pages (from-to)	1651-1656
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	5
DOIs	https://doi.org/10.1002/anie.201410612
State	Published - Jan 26 2015

Keywords

Crystal engineering
Luminescence
Metalorganic frameworks
Microporous materials
Sensors

ASJC Scopus subject areas

General Chemistry
Catalysis

Access to Document

10.1002/anie.201410612

Cite this

Douvali, A., Tsipis, A. C., Eliseeva, S. V., Petoud, S., Papaefstathiou, G. S., Malliakas, C. D., Papadas, I., Armatas, G. S., Margiolaki, I., Kanatzidis, M. G., Lazarides, T., & Manos, M. J. (2015). Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework. Angewandte Chemie - International Edition, 54(5), 1651-1656. https://doi.org/10.1002/anie.201410612

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title = "Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework",

abstract = "The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.",

keywords = "Crystal engineering, Luminescence, Metalorganic frameworks, Microporous materials, Sensors",

author = "Antigoni Douvali and Tsipis, {Athanassios C.} and Eliseeva, {Svetlana V.} and St{\'e}phane Petoud and Papaefstathiou, {Giannis S.} and Malliakas, {Christos D.} and Ioannis Papadas and Armatas, {Gerasimos S.} and Irene Margiolaki and Kanatzidis, {Mercouri G.} and Theodore Lazarides and Manos, {Manolis J.}",

note = "Publisher Copyright: {\textcopyright} 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2015",

month = jan,

day = "26",

doi = "10.1002/anie.201410612",

language = "English (US)",

volume = "54",

pages = "1651--1656",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "5",

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Douvali, A, Tsipis, AC, Eliseeva, SV, Petoud, S, Papaefstathiou, GS, Malliakas, CD, Papadas, I, Armatas, GS, Margiolaki, I, Kanatzidis, MG, Lazarides, T & Manos, MJ 2015, 'Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework', Angewandte Chemie - International Edition, vol. 54, no. 5, pp. 1651-1656. https://doi.org/10.1002/anie.201410612

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T1 - Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

AU - Douvali, Antigoni

AU - Tsipis, Athanassios C.

AU - Eliseeva, Svetlana V.

AU - Petoud, Stéphane

AU - Papaefstathiou, Giannis S.

AU - Malliakas, Christos D.

AU - Papadas, Ioannis

AU - Armatas, Gerasimos S.

AU - Margiolaki, Irene

AU - Kanatzidis, Mercouri G.

AU - Lazarides, Theodore

AU - Manos, Manolis J.

PY - 2015/1/26

Y1 - 2015/1/26

N2 - The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

AB - The development of efficient sensors for the determination of the water content in organic solvents is highly desirable for a number of chemical industries. Presented herein is a Mg2+ metal-organic framework (MOF), which exhibits the remarkable capability to rapidly detect traces of water (0.05-5% v/v) in various organic solvents through an unusual turn-on luminescence sensing mechanism. The extraordinary sensitivity and fast response of this MOF for water, and its reusability make it one of the most powerful water sensors known.

KW - Crystal engineering

KW - Luminescence

KW - Metalorganic frameworks

KW - Microporous materials

KW - Sensors

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JF - Angewandte Chemie - International Edition

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Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Abstract

Keywords

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CCDC 1020009: Experimental Crystal Structure Determination

CCDC 1020008: Experimental Crystal Structure Determination

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Turn-on luminescence sensing and real-time detection of traces of water in organic solvents by a flexible metal-organic framework

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

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Datasets

CCDC 1020009: Experimental Crystal Structure Determination

CCDC 1020008: Experimental Crystal Structure Determination

Cite this